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HomeProduct name listButylmagnesium chloride

Butylmagnesium chloride

Synonym(s):BuMgCl

  • CAS NO.:693-04-9
  • Empirical Formula: C4H9ClMg
  • Molecular Weight: 116.87
  • MDL number: MFCD00000475
  • EINECS: 211-739-5
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2023-06-08 17:06:37
Butylmagnesium chloride Structural

What is Butylmagnesium chloride?

Chemical properties

Butylmagnesium chloride is green-brown to brown solution, it is very active in chemical properties and will react violently when in contact with water and oxygen.

The Uses of Butylmagnesium chloride

n-Butylmagnesium chloride is used in organic synthesis, pharmaceuticals, agrochemicals and dyestuffs.

The Uses of Butylmagnesium chloride

Butylmagnesium chloride (BuMgCl) is a Grignard reagent that can be used:

  • To prevent the formation of passivating surface films on Mg electrodes.
  • For the synthesis of lithium tributylmagnesate complex (n-Bu3MgLi) by reacting with n-BuLi.

Properties of Butylmagnesium chloride

Melting point: -17°C
Boiling point: 66°C
Density  0.962 g/mL at 25 °C
Flash point: 115 °F
storage temp.  2-8°C
form  Solution
color  Green-brown to brown
Water Solubility  reacts
Sensitive  Air & Moisture Sensitive
BRN  3587228
CAS DataBase Reference 693-04-9(CAS DataBase Reference)
EPA Substance Registry System Magnesium, butylchloro- (693-04-9)

Safety information for Butylmagnesium chloride

Signal word Danger
Pictogram(s)
ghs
Flame
Flammables
GHS02
ghs
Corrosion
Corrosives
GHS05
ghs
Exclamation Mark
Irritant
GHS07
ghs
Health Hazard
GHS08
GHS Hazard Statements H225:Flammable liquids
H226:Flammable liquids
H250:Pyrophoric liquids; Pyrorophoric solids
H260:Substances And Mixtures Which, In Contact With Water,Emit Flammable Gases
H261:Substances And Mixtures Which, In Contact With Water,Emit Flammable Gases
H302:Acute toxicity,oral
H303:Acute toxicity,oral
H314:Skin corrosion/irritation
H318:Serious eye damage/eye irritation
H333:Acute toxicity,inhalation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
H336:Specific target organ toxicity,single exposure; Narcotic effects
H351:Carcinogenicity
H371:Specific target organ toxicity, single exposure
H372:Specific target organ toxicity, repeated exposure
Precautionary Statement Codes P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P222:Do not allow contact with air.
P223:Keep away from any possible contact with water, because of violent reaction and possible flash fire.
P233:Keep container tightly closed.
P240:Ground/bond container and receiving equipment.
P260:Do not breathe dust/fume/gas/mist/vapours/spray.
P261:Avoid breathing dust/fume/gas/mist/vapours/spray.
P264:Wash hands thoroughly after handling.
P264:Wash skin thouroughly after handling.
P270:Do not eat, drink or smoke when using this product.
P271:Use only outdoors or in a well-ventilated area.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P231+P232:Handle under inert gas. Protect from moisture.
P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P335+P334:Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages.
P370+P378:In case of fire: Use … for extinction.
P405:Store locked up.
P422:Store contents under …
P402+P404:Store in a dry place. Store in a closed container.

Computed Descriptors for Butylmagnesium chloride

InChIKey UUNGXYVLXYGZKH-UHFFFAOYSA-M

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