Allylmagnesium chloride
- CAS NO.：2622-05-1
- Empirical Formula: C3H5ClMg
- Molecular Weight: 100.83
- MDL number: MFCD00000473
- EINECS: 220-067-1
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-04-23 13:52:06
What is Allylmagnesium chloride?
Chemical properties
clear tan to brown, amber, dark grey, dark green
The Uses of Allylmagnesium chloride
Allylmagnesium chloride has been used in a study of the nucleophilic ring-opening of 2-methyleneaziridines to imines and subsequent conversion to 5,5′-disubstituted hydantoins. It is also used as a reagent for the introduction of the allyl group.
Grignard-reactions: reagent for the introduction of the allyl group.
The Uses of Allylmagnesium chloride
Allylmagnesium chloride has been used in a study of the nucleophilic ring-opening of 2-methyleneaziridines to imines and subsequent conversion to 5,5?-disubstituted hydantoins. It is also used as a reagent for the introduction of the allyl group.
What are the applications of Application
Used in a study of the nucleophilic ring-opening of 2-methyleneaziridines to imines and subsequent conversion to 5,5′-disubstituted hydantoins.
Precautions
It reacts violently with water.
Air & moisture sensitive.
Stable under recommended storage conditions.
Properties of Allylmagnesium chloride
| Melting point: | -21°C |
| Boiling point: | 66°C |
| Density | 0.995 g/mL at 25 °C |
| Flash point: | 1 °F |
| storage temp. | water-free area |
| form | Liquid |
| color | Clear tan to brown, amber, dark gray, dark green or black |
| Water Solubility | vigorous reaction |
| Sensitive | Air & Moisture Sensitive |
| BRN | 3587316 |
| EPA Substance Registry System | Magnesium, chloro-2-propenyl- (2622-05-1) |
Safety information for Allylmagnesium chloride
| Signal word | Danger |
| Pictogram(s) |
 Flame Flammables GHS02  Corrosion Corrosives GHS05  Exclamation Mark Irritant GHS07  Health Hazard GHS08 |
| GHS Hazard Statements |
H225:Flammable liquids H250:Pyrophoric liquids; Pyrorophoric solids H260:Substances And Mixtures Which, In Contact With Water,Emit Flammable Gases H261:Substances And Mixtures Which, In Contact With Water,Emit Flammable Gases H302:Acute toxicity,oral H303:Acute toxicity,oral H314:Skin corrosion/irritation H318:Serious eye damage/eye irritation H333:Acute toxicity,inhalation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation H351:Carcinogenicity H371:Specific target organ toxicity, single exposure H372:Specific target organ toxicity, repeated exposure |
| Precautionary Statement Codes |
P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking. P223:Keep away from any possible contact with water, because of violent reaction and possible flash fire. P233:Keep container tightly closed. P240:Ground/bond container and receiving equipment. P260:Do not breathe dust/fume/gas/mist/vapours/spray. P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P270:Do not eat, drink or smoke when using this product. P271:Use only outdoors or in a well-ventilated area. P280:Wear protective gloves/protective clothing/eye protection/face protection. P231+P232:Handle under inert gas. Protect from moisture. P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. P335+P334:Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages. P370+P378:In case of fire: Use … for extinction. P405:Store locked up. P422:Store contents under … P402+P404:Store in a dry place. Store in a closed container. |
Computed Descriptors for Allylmagnesium chloride
| InChIKey | PLYLAFITHJUEGX-UHFFFAOYSA-M |
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