Boc-D-Phenylglycine
Synonym(s):Boc-Phg-OH;Boc-D-Phg-OH;N-α-t.-Boc-D-phenylglycine;N-α-t.-Boc-L-phenylglycine;Boc-D -α-phenylglycine
- CAS NO.：33125-05-2
- Empirical Formula: C13H17NO4
- Molecular Weight: 251.28
- MDL number: MFCD00062043
- EINECS: 1533716-785-6
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-10-11 17:37:18
What is Boc-D-Phenylglycine?
Chemical properties
White powder
The Uses of Boc-D-Phenylglycine
It is a reagent of choice for assignment of absolute configuration of chiral primary amines by 1H NMR, giving better results than Mosher's acid ((R)-(+)-?-Methoxy-?-(trifluoromethyl)-phenyl-acetic acid. αR)-α-[[(1,1-Dimethylethoxy)carbonyl]amino]-benzeneacetic Acid is D-(+)-2-Phenylglycine with Boc protecting group. (αR)-α-[[(1,1-Dimethylethoxy)carbonyl]amino]-benzeneacetic Acid is used as part of a catalyst combination to catalyze regioselective [4 + 2] cycloadditions of β-substituted cyclic enones and polyconjugated malononitriles. It can also be used to catalyze stereoselective preparation of polyfunctional nitrocyclohexene carboxaldehydes.
Properties of Boc-D-Phenylglycine
| Melting point: | 88-91 °C |
| Boiling point: | 407.2±38.0 °C(Predicted) |
| alpha | -142 º (c=1% in ethanol) |
| Density | 1.182±0.06 g/cm3(Predicted) |
| refractive index | -140 ° (C=1, EtOH) |
| storage temp. | Keep in dark place,Sealed in dry,Room Temperature |
| solubility | DMSO, Methanol |
| form | Crystalline Powder |
| pka | 3.51±0.10(Predicted) |
| color | White |
| optical activity | [α]20/D 141.0±5.0°, c = 1% in ethanol |
| Water Solubility | Insoluble in water. Slightly soluble in DMSO and methanol. |
| BRN | 3033982 |
| CAS DataBase Reference | 33125-05-2(CAS DataBase Reference) |
Safety information for Boc-D-Phenylglycine
| Pictogram(s) |
 Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
| Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P271:Use only outdoors or in a well-ventilated area. P280:Wear protective gloves/protective clothing/eye protection/face protection. P312:Call a POISON CENTER or doctor/physician if you feel unwell. P302+P352:IF ON SKIN: wash with plenty of soap and water. P304+P340:IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. P403+P233:Store in a well-ventilated place. Keep container tightly closed. |
Computed Descriptors for Boc-D-Phenylglycine
Boc-D-Phenylglycine manufacturer
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