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HomeProduct name listBathocuproine

Bathocuproine

Synonym(s):2,9-Dimethyl-4,7-diphenyl-1,10-phenanthroline;BCP

  • CAS NO.:4733-39-5
  • Empirical Formula: C26H20N2
  • Molecular Weight: 360.45
  • MDL number: MFCD00004972
  • EINECS: 225-240-5
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-09-12 12:58:43
Bathocuproine Structural

What is Bathocuproine?

Description

Bathocuproine (BCP) is a wide-band-gap material and has a high electron affinity. When it is embedded into organic electronic devices, bathocuproine acts as an exciton-blocking barrier?which prohibits exciton diffusion process?towards the Al electrode otherwise being quenched. One of the most commonly used buffer layer between acceptor and cathode layers is?bathocuproine. The introduction of the buffer layer can greatly improve the PCE of polymer organic solar cells.?BCP is one of the most popular hole-blocking layer materials that is used in organic electronics, including perovskite solar cells.

Chemical properties

Yellow powder

The Uses of Bathocuproine

Bathocuproine is used as a reagent for the determination of copper. It acts as an exciton blocking barrier which prohibits excitons diffusion process towards the Al electrode otherwise being quenched. It is the most commonly used buffer layer between acceptor and cathode layer.

The Uses of Bathocuproine

It is used as a reagent for the determination of copper. It acts as an exciton blocking barrier which prohibits excitons diffusion process towards the Al electrode otherwise being quenched. It is the most commonly used buffer layer between acceptor and cathode layer.

General Description

TGA/DSC Lot specific scans available upon request

Purification Methods

Purify it by recrystallisation from *benzene. [Smith & Wilkins Anal Chem 25 510 1953, Beilstein 23 III/IV 2160.]

References

[1] Mao, Lingling et al. “Role of Organic Counterion in Lead- and Tin-Based Two-Dimensional Semiconducting Iodide Perovskites and Application in Planar Solar Cells.” Chemistry of Materials 28 (2016): 7781–7792.

Properties of Bathocuproine

Melting point: 279-283 °C(lit.)
Boiling point: 482.47°C (rough estimate)
Density  1.2408 (rough estimate)
refractive index  1.7620 (estimate)
storage temp.  Sealed in dry,Room Temperature
solubility  Benzene (Slightly, Heated), DMSO (Slightly, Heated), Methanol (Slightly, Heated)
form  Powder
pka 5.88±0.30(Predicted)
color  Yellow
Water Solubility  Soluble in methanol (36mg/100ml), ethanol, 2-propanol, bezene, and acetone. Partly miscible in water.
BRN  306714
CAS DataBase Reference 4733-39-5(CAS DataBase Reference)
EPA Substance Registry System 1,10-Phenanthroline, 2,9-dimethyl-4,7-diphenyl- (4733-39-5)

Safety information for Bathocuproine

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H413:Hazardous to the aquatic environment, long-term hazard
Precautionary Statement Codes P273:Avoid release to the environment.

Computed Descriptors for Bathocuproine

InChIKey STTGYIUESPWXOW-UHFFFAOYSA-N

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