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HomeProduct name listDimethyl sebacate

Dimethyl sebacate

Synonym(s):Decanedioic acid 1,10-dimethyl ester;Dimethyl decanedioate;NSC 9415;Sebacic acid dimethyl ester

  • CAS NO.:106-79-6
  • Empirical Formula: C12H22O4
  • Molecular Weight: 230.3
  • MDL number: MFCD00008472
  • EINECS: 203-431-4
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-11-04 13:44:46
Dimethyl sebacate Structural

What is Dimethyl sebacate?

Chemical properties

colourless melt or liquid. Needle-like or plate-like colorless or white crystals. M.P. 38° C. B.P. 293° C. Sp.Gr. 0.99 (liquid). Pleasant and mild-ethereal-fruity odor. Fruity-winey, ethereal Apple-like taste, but very mild.

The Uses of Dimethyl sebacate

Polytetramethylene sebacate was prepared from dimethyl sebacate. Dimethyl sebacate was used in the biosynthesis of oligomeric sebacates as lubricant oils. Dimethyl sebacate was a convenient starting material for cyclization of N-Succinylglycine dimethyl ester.

What are the applications of Application

DMS can be used in the synthesis of decanedihydrazide which can be used as a precursor for isocyanates for the synthesis of thermoplastic polyurethanes. Transesterification of DMS with 2-ethylhexanol can be used to synthesize bis(2-ethylhexyl)sebacate for further use in petroleum based lubricants.

Definition

ChEBI: Dimethyl sebacate is a fatty acid methyl ester that is sebacic acid in which both carboxy groups are replaced by methoxycarbonyl groups. It has a role as a plasticiser and a plant metabolite. It is a fatty acid methyl ester and a diester. It is functionally related to a sebacic acid.

Preparation

By direct estenfication of Sebacic acid and Methanol, usually under azeotropic conditions.

General Description

Dimethyl sebacate (DMS) is a plasticizer that can be synthesized by esterification of sebacic acid. It is from vegetable origin since it is processed from castor oil.

Properties of Dimethyl sebacate

Melting point: 29-31 °C (lit.)
Boiling point: 158 °C/10 mmHg (lit.)
Density  0.988 g/mL at 25 °C (lit.)
vapor pressure  0.08Pa at 25℃
refractive index  1.4355 (estimate)
Flash point: 293 °F
storage temp.  Sealed in dry,Room Temperature
form  powder to lump to clear liquid
color  White or Colorless to Light yellow
Water Solubility  Insoluble in water.
BRN  1785523
Stability: Stable. Incompatible with oxidizing agents, bases. Combustible.
CAS DataBase Reference 106-79-6(CAS DataBase Reference)
NIST Chemistry Reference Decanedioic acid, dimethyl ester(106-79-6)
EPA Substance Registry System Decanedioic acid, 1,10-dimethyl ester (106-79-6)

Safety information for Dimethyl sebacate

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
Precautionary Statement Codes P280:Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352:IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P332+P313:IF SKIN irritation occurs: Get medical advice/attention.
P337+P313:IF eye irritation persists: Get medical advice/attention.

Computed Descriptors for Dimethyl sebacate

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