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HomeProduct name listAMMONIUM TETRATHIOMOLYBDATE

AMMONIUM TETRATHIOMOLYBDATE

Synonym(s):Ammonium thiomolybdate;Diammonium tetrathiomolybdate

AMMONIUM TETRATHIOMOLYBDATE Structural

What is AMMONIUM TETRATHIOMOLYBDATE?

Chemical properties

brown to black iridescent crystalline powder

The Uses of AMMONIUM TETRATHIOMOLYBDATE

Ammonium tetrathiomolybdate is used as an important reagent in synthetic chemistry and as a building block in bioinorganic chemistry. It is used in the treatment of copper toxicosis in animals and in Wilson's disease. It acts as a chelator in vivo to reduce copper levels. It interferes with angiogenesis and reduces tumor growth. Further, it is used in the synthesis of heterometallic sulfide clusters stabilized with dppm [bis(diphenylphosphino)methane] ligands. It is involved in the ring opening of aziridines leading to sulfides and disulfides.

The Uses of AMMONIUM TETRATHIOMOLYBDATE

Ring opening of aziridines leading to sulfides and disulfides.1

What are the applications of Application

Ammonium tetrathiomolybdate is classic building block for transition metal sulfide cluster compounds

Biochem/physiol Actions

Acts as a chelator in vivo to reduce copper levels. Tetrathiomolybdate interferes with angiogenesis and reduces tumor growth. Its mechanism may involve inhibition of NF-κB and downstream cytokines.

Properties of AMMONIUM TETRATHIOMOLYBDATE

Melting point: >300 °C (lit.)
storage temp.  Refrigerator (+4°C)
solubility  Methanol (Slightly), Water (Slightly)
form  Powder or Cyrstals
color  White
Water Solubility  Slightly soluble in water.
Sensitive  Hygroscopic
Exposure limits ACGIH: TWA 0.5 mg/m3
NIOSH: IDLH 1000 mg/m3
CAS DataBase Reference 15060-55-6(CAS DataBase Reference)
EPA Substance Registry System Molybdate(2-), tetrathioxo-, diammonium, (T-4)- (15060-55-6)

Safety information for AMMONIUM TETRATHIOMOLYBDATE

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes P261:Avoid breathing dust/fume/gas/mist/vapours/spray.
P271:Use only outdoors or in a well-ventilated area.
P280:Wear protective gloves/protective clothing/eye protection/face protection.

Computed Descriptors for AMMONIUM TETRATHIOMOLYBDATE

InChIKey PQNOIAHNKHBLRN-UHFFFAOYSA-P

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