4-Chlorostyrene
Synonym(s):1-Chloro-4-ethenyl-bezene;4-Chlorostyrene
- CAS NO.:1073-67-2
- Empirical Formula: C8H7Cl
- Molecular Weight: 138.59
- MDL number: MFCD00000632
- EINECS: 214-028-8
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-10-31 13:32:20
What is 4-Chlorostyrene?
Chemical properties
clear colourless to slightly yellow liquid. The side chain of p-chlorostyrene is a C=C double bond, so its chemical properties are more active. The compound can polymerize slowly at room temperature, and a polymerization inhibitor (stabilizer) can be added for storage.
The Uses of 4-Chlorostyrene
4-Chlorostyrene is used in the preparation of new bis(pyrazolyl)borato olefin complexes of copper(I). It is also employed in the investigation of regioselectivity in the cationic Heck reaction of 4-substituted styrenes. Further, it plays an important role in the preparation of 4-[(4-chloro-phenyl)-thioacetyl]-morpholine.
The Uses of 4-Chlorostyrene
4-Chlorostyrene was used in the following studies:
Study of chemical and biochemical properties of the vinyl group of styrene by the development of structure activity relationships (SAR).
Preparation of new bis(pyrazolyl)borato olefin complexes of copper(I).
To investigate the regioselectivity in the cationic Heck reaction of 4-substituted styrenes.
Preparation
Synthesis of 4-chlorostyrene: carry out catalytic dehydration reaction by 4-chlorophenethylalcohol at 280°C, the used catalyst is a modified aluminum silicate catalyst, and the yield is 80%.
Synthesis Reference(s)
p-Chlorostyrene is commercially produced as a monomer from p-chloroethylbenzene by an oxidation technique. It is also produced as a mixture with o-chlorostyrene.
Journal of the American Chemical Society, 69, p. 852, 1947 DOI: 10.1021/ja01196a033
Tetrahedron Letters, 31, p. 5061, 1990 DOI: 10.1016/S0040-4039(00)97806-7
General Description
4-Chlorostyrene is a para-halogenated styrene derivative. It undergoes graft copolymerization with acrylonitrile (AN) onto ethylene-propylene-diene terpolymer (EPDM) in the presence of benzoyl peroxide (initiator).
Properties of 4-Chlorostyrene
Melting point: | -16 °C |
Boiling point: | 192 °C(lit.) |
Density | 1.155 g/mL at 25 °C(lit.) |
vapor pressure | 0.68 mm Hg ( 20 °C) |
refractive index | n |
Flash point: | 140 °F |
storage temp. | 2-8°C |
form | Liquid |
color | Clear colorless to slightly yellow |
Specific Gravity | 1.155 |
Water Solubility | Immiscible with water. |
BRN | 1098859 |
CAS DataBase Reference | 1073-67-2(CAS DataBase Reference) |
NIST Chemistry Reference | Benzene, 1-chloro-4-ethenyl-(1073-67-2) |
EPA Substance Registry System | Benzene, 1-chloro-4-ethenyl- (1073-67-2) |
Safety information for 4-Chlorostyrene
Signal word | Warning |
Pictogram(s) |
Exclamation Mark Irritant GHS07 Environment GHS09 |
GHS Hazard Statements |
H315:Skin corrosion/irritation H411:Hazardous to the aquatic environment, long-term hazard |
Precautionary Statement Codes |
P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P273:Avoid release to the environment. P280:Wear protective gloves/protective clothing/eye protection/face protection. P302+P352:IF ON SKIN: wash with plenty of soap and water. P332+P313:IF SKIN irritation occurs: Get medical advice/attention. |
Computed Descriptors for 4-Chlorostyrene
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