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HomeProduct name list4-Chlorostyrene

4-Chlorostyrene

Synonym(s):1-Chloro-4-ethenyl-bezene;4-Chlorostyrene

  • CAS NO.:1073-67-2
  • Empirical Formula: C8H7Cl
  • Molecular Weight: 138.59
  • MDL number: MFCD00000632
  • EINECS: 214-028-8
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-10-31 13:32:20
4-Chlorostyrene Structural

What is 4-Chlorostyrene?

Chemical properties

clear colourless to slightly yellow liquid. The side chain of p-chlorostyrene is a C=C double bond, so its chemical properties are more active. The compound can polymerize slowly at room temperature, and a polymerization inhibitor (stabilizer) can be added for storage.

The Uses of 4-Chlorostyrene

4-Chlorostyrene is used in the preparation of new bis(pyrazolyl)borato olefin complexes of copper(I). It is also employed in the investigation of regioselectivity in the cationic Heck reaction of 4-substituted styrenes. Further, it plays an important role in the preparation of 4-[(4-chloro-phenyl)-thioacetyl]-morpholine.

The Uses of 4-Chlorostyrene

4-Chlorostyrene was used in the following studies:
Study of chemical and biochemical properties of the vinyl group of styrene by the development of structure activity relationships (SAR).
Preparation of new bis(pyrazolyl)borato olefin complexes of copper(I).
To investigate the regioselectivity in the cationic Heck reaction of 4-substituted styrenes.

Preparation

Synthesis of 4-chlorostyrene: carry out catalytic dehydration reaction by 4-chlorophenethylalcohol at 280°C, the used catalyst is a modified aluminum silicate catalyst, and the yield is 80%.

Synthesis Reference(s)

p-Chlorostyrene is commercially produced as a monomer from p-chloroethylbenzene by an oxidation technique. It is also produced as a mixture with o-chlorostyrene.
Journal of the American Chemical Society, 69, p. 852, 1947 DOI: 10.1021/ja01196a033
Tetrahedron Letters, 31, p. 5061, 1990 DOI: 10.1016/S0040-4039(00)97806-7

General Description

4-Chlorostyrene is a para-halogenated styrene derivative. It undergoes graft copolymerization with acrylonitrile (AN) onto ethylene-propylene-diene terpolymer (EPDM) in the presence of benzoyl peroxide (initiator).

Properties of 4-Chlorostyrene

Melting point: -16 °C
Boiling point: 192 °C(lit.)
Density  1.155 g/mL at 25 °C(lit.)
vapor pressure  0.68 mm Hg ( 20 °C)
refractive index  n20/D 1.565(lit.)
Flash point: 140 °F
storage temp.  2-8°C
form  Liquid
color  Clear colorless to slightly yellow
Specific Gravity 1.155
Water Solubility  Immiscible with water.
BRN  1098859
CAS DataBase Reference 1073-67-2(CAS DataBase Reference)
NIST Chemistry Reference Benzene, 1-chloro-4-ethenyl-(1073-67-2)
EPA Substance Registry System Benzene, 1-chloro-4-ethenyl- (1073-67-2)

Safety information for 4-Chlorostyrene

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
ghs
Environment
GHS09
GHS Hazard Statements H315:Skin corrosion/irritation
H411:Hazardous to the aquatic environment, long-term hazard
Precautionary Statement Codes P264:Wash hands thoroughly after handling.
P264:Wash skin thouroughly after handling.
P273:Avoid release to the environment.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352:IF ON SKIN: wash with plenty of soap and water.
P332+P313:IF SKIN irritation occurs: Get medical advice/attention.

Computed Descriptors for 4-Chlorostyrene

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