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HomeProduct name list2-(Di-tert-butylphosphino)biphenyl

2-(Di-tert-butylphosphino)biphenyl

Synonym(s):(2-Biphenyl)di-tert-butylphosphine;(2-Biphenylyl)di-tert-butylphosphine;2-(Di-tert-butylphosphino)biphenyl

  • CAS NO.:224311-51-7
  • Empirical Formula: C20H27P
  • Molecular Weight: 298.4
  • MDL number: MFCD01862440
  • EINECS: 607-074-9
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-07-18 18:48:45
2-(Di-tert-butylphosphino)biphenyl Structural

What is 2-(Di-tert-butylphosphino)biphenyl?

Chemical properties

white to light yellow crystal powde

The Uses of 2-(Di-tert-butylphosphino)biphenyl

suzuki reaction

The Uses of 2-(Di-tert-butylphosphino)biphenyl

2-(Di-tert-butylphosphino)biphenyl (also known as JohnPhos) is a Buchwald ligand that is highly efficient in palladium-catalyzed reactions.

General Description

JohnPhos is a Buchwald′s sterically bulky biaryl phosphine ligand. It is a reactive dialkylbiaryl phosphine ligand which catalyzes the carbon-nitrogen bond-forming reactions. Coordination chemistry of gold catalysts bearing JohnPhos as ligand has been investigated by NMR spectroscopy.

Properties of 2-(Di-tert-butylphosphino)biphenyl

Melting point: 86-88 °C (lit.)
Boiling point: 405.5±24.0 °C(Predicted)
Density  1 g/cm3
storage temp.  Inert atmosphere,Room Temperature
solubility  Chloroform (Slightly), Dichloromethane (Slightly), DMSO (Slightly, Heated, Sonic
form  Crystals or Crystalline Powder
color  White
Water Solubility  Insoluble
BRN  8322131
Stability: Air Sensitive
CAS DataBase Reference 224311-51-7(CAS DataBase Reference)

Safety information for 2-(Di-tert-butylphosphino)biphenyl

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
H413:Hazardous to the aquatic environment, long-term hazard
Precautionary Statement Codes P264:Wash hands thoroughly after handling.
P264:Wash skin thouroughly after handling.
P280:Wear protective gloves/protective clothing/eye protection/face protection.

Computed Descriptors for 2-(Di-tert-butylphosphino)biphenyl

InChIKey CNXMDTWQWLGCPE-UHFFFAOYSA-N

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