2-Chloro-3-pyridylboronic acid
Synonym(s):(2-Chloro-3-pyridyl)boronic acid;(2-Chloropyridin-3-yl)boronic acid;Dihydroxy(2-chloro-3-pyridyl)borane
- CAS NO.：381248-04-0
- Empirical Formula: C5H5BClNO2
- Molecular Weight: 157.36
- MDL number: MFCD03094997
- EINECS: 624-435-6
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-04-23 13:52:06
What is 2-Chloro-3-pyridylboronic acid?
Chemical properties
White solid
The Uses of 2-Chloro-3-pyridylboronic acid
Reactant for:
- Synthesis of Et canthinone-3-carboxylates from Et 4-bromo-6-methoxy-1,5-naphthyridine-3-carboxylate via a Pd-catalyzed Suzuki-Miyaura coupling and a Cu-catalyzed amidation reaction
- Preparation of arylmethylpyrrolidinylmethanols and amine derivatives via reaction with MIDA followed by Suzuki reaction with halides or amination with amines
- Preparation of arylazabicyclooctane derivatives as potential arginine vasopressin receptor antagonists
- Regioselective preparation of halo-oligopyridines and oligopyridines by the Suzuki-Miyaura cross-coupling reaction
Properties of 2-Chloro-3-pyridylboronic acid
| Melting point: | 121-134 °C |
| Boiling point: | 349.3±52.0 °C(Predicted) |
| Density | 1.41±0.1 g/cm3(Predicted) |
| storage temp. | 2-8°C |
| solubility | soluble in Methanol |
| form | Crystalline Powder |
| pka | 6.59±0.58(Predicted) |
| color | White |
| BRN | 9119913 |
| CAS DataBase Reference | 381248-04-0(CAS DataBase Reference) |
Safety information for 2-Chloro-3-pyridylboronic acid
| Signal word | Warning |
| Pictogram(s) |
 Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
| Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P271:Use only outdoors or in a well-ventilated area. P280:Wear protective gloves/protective clothing/eye protection/face protection. P302+P352:IF ON SKIN: wash with plenty of soap and water. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for 2-Chloro-3-pyridylboronic acid
| InChIKey | VRDAOVQZVXYRNH-UHFFFAOYSA-N |
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