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HomeProduct name list1,3-Dichloropropane

1,3-Dichloropropane

Synonym(s):Trimethylene dichloride

  • CAS NO.:142-28-9
  • Empirical Formula: C3H6Cl2
  • Molecular Weight: 112.99
  • MDL number: MFCD00000999
  • EINECS: 205-531-3
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-10-24 21:11:45
1,3-Dichloropropane Structural

What is 1,3-Dichloropropane?

Chemical properties

1,3-Dichloropropene occurs as a clear colourless liquid with a sweet chloroform-like odor. It is soluble in alcohol and ether, dissolves in water (0.27g/100ml). The half-life of 1,3-dichloropropene in ambient air may range from 7 to 50 hours.

The Uses of 1,3-Dichloropropane

1,3-Dichloropropane is used as an intermediate in organic synthesis. It is also used as solvent, detergent and chromatographic analysis. Further, it is used to prepare 3,7-dithia-nonanedioic acid by reacting with mercaptoacetic acid.

Definition

ChEBI: 1,3-dichloropropane is a chloroalkane that is propane in which a hydrogen from each of the terminal methyl groups has been replaced by a chlorine. It has a role as an environmental contaminant and a nematicide. It is a chloroalkane and a chlorohydrocarbon.

Preparation

1,3-Dichloropropane is obtained by the action of propylene glycol with hydrochloric acid.
1,3-Dichloropropane synthesis: A process for the preparation of 1,3-dichloropropane by reacting bis(3-hydroxypropyl)ether with hydrogen chloride, optionally in the presence of tertiary basic nitrogen compounds or other tertiary aliphatic bases as catalysts, distilling off the 1,3-dichloropropane and the water of reaction and working up the two phases.
Process for the preparation of 1,3-dichloropropane

Synthesis Reference(s)

The Journal of Organic Chemistry, 29, p. 194, 1964 DOI: 10.1021/jo01024a045

General Description

1,3-dichloropropane is a colorless watery liquid with a sweet odor. Sinks in water. Produces irritating vapor. (USCG, 1999)

Air & Water Reactions

Highly flammable.

Reactivity Profile

Halogenated aliphatic compounds, such as 1,3-Dichloropropane, are moderately or very reactive. Reactivity generally decreases with increased degree of substitution of halogen for hydrogen atoms. Low molecular weight haloalkanes are highly flammable and can react with some metals to form dangerous products. Materials in this group are incompatible with strong oxidizing and reducing agents. Also, they are incompatible with many amines, nitrides, azo/diazo compounds, alkali metals, and epoxides.

Health Hazard

INHALATION: May cause some central nervous system depression. EYES: May cause some pain and irritation. SKIN: Mild irritation.

Safety Profile

Moderately toxic by ingestion. Mutation data reported. A very dangerous fire hazard when exposed to heat or flame. When heated to decomposition it emits highly toxic fumes of Cl and phosgene. See also CHLORINATED HYDROCARBONS, ALIPHATIC; and PROPYLENE DICHLORIDE.

Properties of 1,3-Dichloropropane

Melting point: −99 °C(lit.)
Boiling point: 120-122 °C(lit.)
Density  1.19 g/mL at 25 °C(lit.)
vapor pressure  24-24.265hPa at 20-25℃
refractive index  n20/D 1.448(lit.)
Flash point: 90 °F
storage temp.  Refrigerator
solubility  Chloroform (Slightly), Ethyl Acetate (Slightly)
form  Liquid
color  Clear colorless
Water Solubility  0.8 g/L (20 ºC)
BRN  505960
Dielectric constant 9.5099999999999998
CAS DataBase Reference 142-28-9(CAS DataBase Reference)
NIST Chemistry Reference Propane, 1,3-dichloro-(142-28-9)
EPA Substance Registry System 1,3-Dichloropropane (142-28-9)

Safety information for 1,3-Dichloropropane

Signal word Warning
Pictogram(s)
ghs
Flame
Flammables
GHS02
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H226:Flammable liquids
H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P302+P352:IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for 1,3-Dichloropropane

InChIKey YHRUOJUYPBUZOS-UHFFFAOYSA-N

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