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HomeProduct name list1-Bromo-3-methylbutane

1-Bromo-3-methylbutane

Synonym(s):Isoamyl bromide;Isopentyl bromide

  • CAS NO.:107-82-4
  • Empirical Formula: C5H11Br
  • Molecular Weight: 151.04
  • MDL number: MFCD00000253
  • EINECS: 203-522-9
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-12-18 14:15:32
1-Bromo-3-methylbutane Structural

What is 1-Bromo-3-methylbutane?

Chemical properties

clear colourless liquid

The Uses of 1-Bromo-3-methylbutane

1-Bromo-3-methylbutane was used in the synthesis of 1-(3-methylbutyl)pyrrole and in the production of pentyl peroxy radical by direct photolysis production method. It was also used as extraction solvent for determination of polycyclic aromatic hydrocarbons in water samples using liquid-liquid microextraction combined with gas chromatography-mass spectrometry. It is also used as an alkyl halide and organic synthesis reagent.

The Uses of 1-Bromo-3-methylbutane

An alkyl halide and organic synthesis reagent.

The Uses of 1-Bromo-3-methylbutane

In organic synthesis.

What are the applications of Application

1-Bromo-3-methylbutane is an alkyl halide and organic synthesis reagent

Synthesis Reference(s)

Journal of the American Chemical Society, 96, p. 8115, 1974 DOI: 10.1021/ja00833a048
Organic Syntheses, Coll. Vol. 1, p. 25, 1941

General Description

A colorless liquid. Flash point 21°F. Slightly soluble in water and denser than water. Vapors are heavier than air.

Air & Water Reactions

Highly flammable. Slightly soluble in water and denser than water.

Reactivity Profile

Halogenated aliphatic compounds, such as 1-Bromo-3-methylbutane, are moderately or very reactive. Reactivity generally decreases with increased degree of substitution of halogen for hydrogen atoms. Low molecular weight haloalkanes are highly flammable and can react with some metals to form dangerous products. Materials in this group are incompatible with strong oxidizing and reducing agents. Also, they are incompatible with many amines, nitrides, azo/diazo compounds, alkali metals, and epoxides. Gives toxic fumes of bromine when burned.

Health Hazard

May cause toxic effects if inhaled or absorbed through skin. Inhalation or contact with material may irritate or burn skin and eyes. Fire will produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.

Fire Hazard

HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.

Safety Profile

Moderately toxic by intraperitoneal route. Flammable liquid. Dangerous fire hazard when exposed to heat or flame. When heated to decomposition it emits toxic fumes of Br-. See also BROMIDES.

Purification Methods

Shake the bromide with conc H2SO4, wash with water, dry with K2CO3 and fractionally distil it. [Beilstein 1 IV 378.]

Properties of 1-Bromo-3-methylbutane

Melting point: -112 °C
Boiling point: 120-121 °C(lit.)
Density  1.261 g/mL at 25 °C(lit.)
refractive index  n20/D 1.4409(lit.)
Flash point: 90 °F
storage temp.  2-8°C
solubility  H2O: slightly soluble at 16.5°C (0.02g/100ml)
form  Liquid
color  Clear colorless
Water Solubility  0.2 g/L (16 ºC)
Merck  14,5114
BRN  773652
Dielectric constant 6.1(24℃)
CAS DataBase Reference 107-82-4(CAS DataBase Reference)
NIST Chemistry Reference Butane, 1-bromo-3-methyl-(107-82-4)
EPA Substance Registry System Butane, 1-bromo-3-methyl- (107-82-4)

Safety information for 1-Bromo-3-methylbutane

Signal word Danger
Pictogram(s)
ghs
Flame
Flammables
GHS02
ghs
Exclamation Mark
Irritant
GHS07
ghs
Environment
GHS09
GHS Hazard Statements H225:Flammable liquids
H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
H411:Hazardous to the aquatic environment, long-term hazard
Precautionary Statement Codes P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P233:Keep container tightly closed.
P240:Ground/bond container and receiving equipment.
P273:Avoid release to the environment.
P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for 1-Bromo-3-methylbutane

InChIKey YXZFFTJAHVMMLF-UHFFFAOYSA-N

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