Bromocyclohexane
Synonym(s):Cyclohexyl bromide
- CAS NO.:108-85-0
- Empirical Formula: C6H11Br
- Molecular Weight: 163.06
- MDL number: MFCD00003819
- EINECS: 203-622-2
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-11-05 19:05:58
What is Bromocyclohexane?
Chemical properties
colourless liquid
The Uses of Bromocyclohexane
Bromocyclohexane has been used to study the ionization of equatorial and axial conformational isomers of the chair-bromocyclohexane using vacuum ultraviolet mass-analyzed threshold ionization spectroscopy.
What are the applications of Application
Bromocyclohexane is used to study the ionization of equatorial and axial conformational isomers of the chair-bromocyclohexane
Preparation
Bromocyclohexane is synthesized by the reaction of cycloethanol and hydrobromic acid.
Synthesis Reference(s)
Canadian Journal of Chemistry, 50, p. 3109, 1972 DOI: 10.1139/v72-498
Journal of the American Chemical Society, 112, p. 8212, 1990 DOI: 10.1021/ja00178a080
The Journal of Organic Chemistry, 45, p. 1638, 1980 DOI: 10.1021/jo01297a020
General Description
Axial conformer of bromocyclohexane forms inclusion complexes with 9,9′-bianthryl and exhibits a weak 1,3 diaxial Cl...H interaction. It participates in the alkylation reaction of of para-xylene in the presence of graphite as catalyst to yield hydrocarbon.
Purification Methods
Shake the bromide with 60% aqueous HBr to remove the free alcohol. After removing excess HBr, the sample is dried and fractionally distilled. [IR: Roberts & Chambers J Am Chem Soc 73 5031 1951, Beilstein 5 III 48, 5 IV 67.]
Properties of Bromocyclohexane
Melting point: | -57°C |
Boiling point: | 166-167 °C (lit.) |
Density | 1.324 g/mL at 25 °C (lit.) |
vapor density | 5.62 (vs air) |
refractive index | n |
Flash point: | 145 °F |
storage temp. | Sealed in dry,Room Temperature |
solubility | Miscible with ethanol, ether, acetone, benzene and carbon tetrachloride. |
form | Liquid |
color | Clear colorless to light yellow |
Specific Gravity | approximate 1.33 (20℃) |
Odor | Unpleasant Odor |
Water Solubility | insoluble |
Sensitive | Air & Light Sensitive |
Merck | 14,2730 |
BRN | 1098373 |
Dielectric constant | 7.9(25℃) |
Stability: | Stable. Combustible. Incompatible with strong oxidizing agents, strong bases. |
CAS DataBase Reference | 108-85-0(CAS DataBase Reference) |
NIST Chemistry Reference | Cyclohexane, bromo-(108-85-0) |
EPA Substance Registry System | Cyclohexane, bromo- (108-85-0) |
Safety information for Bromocyclohexane
Signal word | Warning |
Pictogram(s) |
Exclamation Mark Irritant GHS07 |
GHS Hazard Statements |
H227:Flammable liquids H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
Precautionary Statement Codes |
P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking. P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P280:Wear protective gloves/protective clothing/eye protection/face protection. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. P405:Store locked up. P403+P235:Store in a well-ventilated place. Keep cool. P501:Dispose of contents/container to..… |
Computed Descriptors for Bromocyclohexane
InChIKey | AQNQQHJNRPDOQV-UHFFFAOYSA-N |
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