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HomeProduct name list(-)-Taddol

(-)-Taddol

Synonym(s):(−)-trans-α,α′-(2,2-Dimethyl-1,3-dioxolane-4,5-diyl)bis(diphenylmethanol);(−)-2,3-O-Isopropylidene-1,1,4,4-tetraphenyl-L-threitol;(4R,5R)-4,5-Bis(diphenylhydroxymethyl)-2,2-dimethyldioxolane;1,1,4,4-Tetraphenyl-2,3-O-isopropylidene-L-threitol;TADDOL

(-)-Taddol Structural

What is (-)-Taddol?

Chemical properties

white to light yellow crystal powde

The Uses of (-)-Taddol

Hydrogen-bonding organocatalyst examined in terms of acidity, deprotonation enthalpies and hydrogen bonding

Catalyst involved in synthesis of cyclopropylamines via addition reactions of Grignard reagents to amides

Reactant or reagent involved in:

  • Enantioswitching of catalytic asymmetric hydroboration
  • Synthesis of derivative ligands for asymmetric hydroformylation of alkenes
  • Amide-directed catalytic asymmetric hydroboration of trisubstituted alkenes
  • Addition of deactivated alkyl Grignard reagents to aldehydes

Properties of (-)-Taddol

Melting point: 193-195 °C(lit.)
Boiling point: 489.39°C (rough estimate)
alpha  -65.5 º (c=1, CHCl3)
Density  1.0864 (rough estimate)
refractive index  -69 ° (C=1, CHCl3)
storage temp.  Inert atmosphere,Room Temperature
form  Powder
pka 12.28±0.29(Predicted)
color  white
optical activity [α]19/D 62.6°, c = 1 in chloroform
BRN  3657855
CAS DataBase Reference 93379-48-7(CAS DataBase Reference)

Safety information for (-)-Taddol

Computed Descriptors for (-)-Taddol

InChIKey RNSJHECWLNVNFE-KYJUHHDHSA-N

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