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HomeProduct name listD-(-)-Tartaric Acid

D-(-)-Tartaric Acid

Synonym(s):(2R,3R)-(+)-Tartaric acid;(2S,3S)-(-)-Tartaric acid;L-(+)-Tartaric acid;L-Threaric acid;D-(-)-Tartaric acid

  • CAS NO.:147-71-7
  • Empirical Formula: C4H6O6
  • Molecular Weight: 150.09
  • MDL number: MFCD00004238
  • EINECS: 205-695-6
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-11-18 17:01:59
D-(-)-Tartaric Acid  Structural

What is D-(-)-Tartaric Acid ?

Chemical properties

D-Tartaric acid is a white crystalline dicarboxylic acid found in many plants, particularly tamarinds and grapes. It is an acidulant that occurs naturally in grapes. It is hygroscopic and rapidly soluble, with a solubility of 150 g in 100 ml of distilled water at 25°c. It has a slightly tarter taste than citric acid, with a tartness equivalent of 0.8–0.9. It augments the flavor of fruits in which it is a natural constituent. It is used in grapeand limeflavored beverages and grape-flavored jellies. It is used as an acidulant in baking powder and as a synergist with antioxidants to prevent rancidity.

The Uses of D-(-)-Tartaric Acid

D-(-)-Tartaric acid is used as a resolving agent in organic synthesis. It is used as a precursor for the preparation of its ester derivatives like D-tartaric acid diethyl ester, D-tartaric acid dimethyl ester and D-tartaric acid diiso-propyl ester. It finds application in the synthesis of chiral aziridine derivative, a common intermediate for the preparation of hydroxyethylamine class HIV protease inhibitors viz. as saquinavir, amprenavir and nelfinavir. It is widely used in the food industry as a beer foaming agent, for food acidity regulations and as a flavoring agent.

Definition

ChEBI: D-tartaric acid is the D-enantiomer of tartaric acid. It has a role as an Escherichia coli metabolite. It is a conjugate acid of a D-tartrate(1-). It is an enantiomer of a L-tartaric acid.

Biotechnological Production

Tartaric acid is generally produced from crude tartar and lees, which are byproducts of wine production. However, there are a few reports of fermentative production of tartaric acid by Gluconobacter suboxydans growing on Glucose or sorbitol. Vanadate plays a central role in this process. The microorganism forms 5-keto-D-gluconic acid, which is oxidized to tartaric acid. The vanadium catalyzes this reaction. Product concentrations up to 2.96 g.L-1 have been observed after 3 days of fermentation.

General Description

D-(-)-Tartaric acid is a polycrystalline solid, widely used as food additive. It has been reported to exhibit piezoelectric effect.

Purification Methods

Crystallise the acid from distilled H2O or *benzene/diethyl ether containing 5% of pet ether (b 60-80o) (1:1). Soxhlet extraction with diethyl ether has been used to remove an impurity absorbing at 265nm. It has also been crystallised from absolute EtOH/hexane and dried in a vacuum for 18hours [Kornblum & Wade J Org Chem 52 5301 1987]. [Beilstein 3 IV 1229.]

Properties of D-(-)-Tartaric Acid

Melting point: 172-174 °C(lit.)
Boiling point: 191.59°C (rough estimate)
alpha  -12.1 º (c=20, H2O)
Density  1,8 g/cm3
refractive index  -12.5 ° (C=5, H2O)
Flash point: 210 °C
storage temp.  Store below +30°C.
solubility  water: soluble100mg/mL, clear, colorless
form  Crystals or Crystalline Powder
pka 3.0, 4.4(at 25℃)
color  White
Odor odorless
optical activity [α]20/D 13.5±0.5°, c = 10% in H2O
Water Solubility  1394 g/L (20 ºC)
Sensitive  Light Sensitive
Merck  14,9068
BRN  1725145
Dielectric constant 35.9(-10℃)
Stability: Stable. Incompatible with oxidizing agents, bases, reducing agents. Combustible.
CAS DataBase Reference 147-71-7(CAS DataBase Reference)
NIST Chemistry Reference D-Tartaric acid(147-71-7)
EPA Substance Registry System Butanedioic acid, 2,3-dihydroxy-, (2S,3S)- (147-71-7)

Safety information for D-(-)-Tartaric Acid

Signal word Danger
Pictogram(s)
ghs
Corrosion
Corrosives
GHS05
GHS Hazard Statements H318:Serious eye damage/eye irritation
Precautionary Statement Codes P280:Wear protective gloves/protective clothing/eye protection/face protection.

Computed Descriptors for D-(-)-Tartaric Acid

InChIKey FEWJPZIEWOKRBE-LWMBPPNESA-N

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