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HomeProduct name listZIRCONIUM N-PROPOXIDE

ZIRCONIUM N-PROPOXIDE

Synonym(s):Tetrapropyl zirconate

  • CAS NO.:23519-77-9
  • Empirical Formula: C12H28O4Zr
  • Molecular Weight: 327.57
  • MDL number: MFCD00015307
  • EINECS: 245-711-9
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-11-21 15:02:05
ZIRCONIUM N-PROPOXIDE Structural

What is ZIRCONIUM N-PROPOXIDE?

Chemical properties

slightly viscous colorless to pale yellow solution

The Uses of ZIRCONIUM N-PROPOXIDE

Zirconium(IV) n-propoxide is used as a precursor in the production of zirconia. It is also used to study the thermophysical properties like thermal conductivity and thermal effusivity of hybrid films and thereby adjusting optic properties of the films.

General Description

A yellow-colored liquid with an alcohol-like odor. Has about the same density as water and is insoluble in water. Flash point below 141°F. Vapors are heavier than air. May be irritating to skin, eyes, and mucous membranes.

Air & Water Reactions

Flammable. Insoluble in water.

Reactivity Profile

Organometallics, such as TETRA-N-PROPYL ZIRCONATE, are reactive with many other groups. Incompatible with acids and bases. Organometallics are good reducing agents and therefore incompatible with oxidizing agents. Often reactive with water to generate toxic or flammable gases.

Health Hazard

Inhalation or contact with material may irritate or burn skin and eyes. Fire may produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.

Purification Methods

Although it was reported that it could not be crystallised or sublimed even at 150o/10-4mm [Bradley & Wardlaw J Chem Soc 280 1951], the propoxide, when properly prepared, has been purifed by distillation in a high vacuum [Bradley et al. J Chem Soc 2025 1953]. [Beilstein 1 IV 1420.]

Properties of ZIRCONIUM N-PROPOXIDE

Boiling point: 208 °C0.1 mm Hg
Density  1.058 g/mL at 20 °C
vapor pressure  19.4hPa at 20℃
refractive index  n20/D 1.454
Flash point: 83 °F
form  Slightly Viscous Solution
color  Colorless to yellow to light amber
Specific Gravity 1.05
Water Solubility  Not miscible in water.
Sensitive  Moisture Sensitive
Hydrolytic Sensitivity 7: reacts slowly with moisture/water
BRN  3679533
Exposure limits ACGIH: TWA 5 mg/m3; STEL 10 mg/m3
NIOSH: IDLH 25 mg/m3; TWA 5 mg/m3; STEL 10 mg/m3
CAS DataBase Reference 23519-77-9(CAS DataBase Reference)
EPA Substance Registry System 1-Propanol, zirconium(4+) salt (23519-77-9)

Safety information for ZIRCONIUM N-PROPOXIDE

Signal word Danger
Pictogram(s)
ghs
Flame
Flammables
GHS02
ghs
Corrosion
Corrosives
GHS05
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H226:Flammable liquids
H318:Serious eye damage/eye irritation
H336:Specific target organ toxicity,single exposure; Narcotic effects
Precautionary Statement Codes P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P233:Keep container tightly closed.
P240:Ground/bond container and receiving equipment.
P241:Use explosion-proof electrical/ventilating/lighting/…/equipment.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for ZIRCONIUM N-PROPOXIDE

InChIKey XPGAWFIWCWKDDL-UHFFFAOYSA-N

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