XPhos Pd G2
Synonym(s):2nd Generation XPhos Precatalyst;Chloro(2-dicyclohexylphosphino-2′,4′,6′-triisopropyl-1,1′-biphenyl)[2-(2′-amino-1,1′-biphenyl)]palladium(II);X-Phos aminobiphenyl palladium chloride precatalyst;XPhos-Pd-G2
- CAS NO.:1310584-14-5
- Empirical Formula: C45H58ClNPPd+2
- Molecular Weight: 785.795481
- MDL number: MFCD28100489
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-03-18 16:05:02
What is XPhos Pd G2?
The Uses of XPhos Pd G2
XPhos Pd G2 is a used as a catalyst in chemical reactions.
The Uses of XPhos Pd G2
XPhos Pd G2 was employed as catalyst in the following reactions:
- Palladium-catalyzed Suzuki-Miyaura coupling reactions of potassium organotrifluoroborates and sulfamates.
- Suzuki-Miyaura cross-coupling reactions of sensitive aryl and heteroarylboronic acids.
- Synthesis of potassium Boc-protected secondary aminomethyltrifluoroborates, via Suzuki-Miyaura cross-coupling reaction.
General Description
XPhos Pd G2 is a bulky monodentate biaryl ligand. It is a Buchwald′s 2nd generation preformed catalyst. It undergoes rapid reductive elimination to form a reactive, monoligated Pd(0) species.
Properties of XPhos Pd G2
Melting point: | 202-210°C |
storage temp. | under inert gas (nitrogen or Argon) at 2-8°C |
form | Powder |
color | white |
Safety information for XPhos Pd G2
Computed Descriptors for XPhos Pd G2
InChIKey | USWOVTRTHZODCW-UHFFFAOYSA-N |
SMILES | C1(C2=CC=CC=C2N)=CC=CC=C1[Pd+2].C1(C2=C(C(C)C)C=C(C(C)C)C=C2C(C)C)=CC=CC(Cl)=C1P(C1CCCCC1)C1CCCCC1 |
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product: 1310584-14-5 Palladium-Xphos 98%
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SPhos Pd G2
Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II)
BIS(DI-TERT-BUTYL(4-DIMETHYLAMINOPHENYL)PHOSPHINE)DICHLOROPALLADIUM
Bis(diphenylphosphinophenyl)ether palladium (II) dichloride
RuPhos Pd G3
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