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HomeProduct name listSPhos Pd G2

SPhos Pd G2

Synonym(s):2nd Generation SPhos Precatalyst;Chloro(2-dicyclohexylphosphino-2′,6′-dimethoxy-1,1′-biphenyl)[2-(2′-amino-1,1′-biphenyl)]palladium(II);SPhos-Pd-G2

SPhos Pd G2 Structural

What is SPhos Pd G2?

The Uses of SPhos Pd G2

Application in Suzuki-Miyaura coupling:

  • Self-arylation of 1-alkyl-3-bromo-2-phenyl-2,1-borazaronaphthalenes to form 2,1-borazaronaphthols.
  • Suzuki–Miyaura coupling of [Ru(bpy)2]+ with 4-carboxyphenylboronic acid.
  • Suzuki–Miyaura coupling of β-borylated porphyrins with 2-iodoaniline.

General Description

SPhos Pd G2 is a second generation (G2) precatalyst in which phenethylamine based backbone of the (G1) complex is substituted with a biphenyl-based ligand. This improvement on the previous generation allows creating the active palladium species at room temperature with weak phosphate or carbonate bases. The catalyst proves remarkably adept at achieving a variety of Suzuki-Miyaura couplings among other cross-coupling reactions.

Properties of SPhos Pd G2

Melting point: 218°C (dec.)
form  Powder
color  white

Safety information for SPhos Pd G2

Computed Descriptors for SPhos Pd G2

InChIKey PYMQIHHZINPLDV-UHFFFAOYSA-N
SMILES P(C1CCCCC1)(C1CCCCC1)(C1C=CC=CC=1C1C(=CC=CC=1OC)OC)[Pd+2]1(NC2=CC=CC=C2C2=CC=CC=[C-]12)[Cl-]

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