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HomeProduct name listRuPhos Pd G3

RuPhos Pd G3

Synonym(s):(2-Dicyclohexylphosphino-2′,6′-diisopropoxy-1,1′-biphenyl)[2-(2′-amino-1,1′-biphenyl)]palladium(II) methanesulfonate;RuPhos-G3-Palladacycle;RuPhos-Pd-G3

  • CAS NO.:1445085-77-7
  • Empirical Formula: C43H57NO5PPdS-
  • Molecular Weight: 837.375141
  • MDL number: MFCD22572684
  • Update Date: 2024-03-18 16:04:41
RuPhos Pd G3 Structural

What is RuPhos Pd G3?

The Uses of RuPhos Pd G3

RuPhos Pd G3 can be used as a pre-catalyst in the following protocols:

  • Palladium-catalyzed Suzuki coupling of 5-p-toluenesulfonyltetrazoles with arylboronic acids to synthesize 1,5-disubstituted tetrazoles.
  • Suzuki-Miyaura catalyst-transfer polycondensation (SCTP) of 3-alkylthiophenes in the presence of N-methylimidodiacetic (MIDA)-boronate monomers.
  • Suzuki-Miyaura-cross-coupling of aminothiophenes.

General Description

RuPhos Pd G3 is a third generation (G3) Buchwald precatalyst that can be used in cross-coupling reactions for the formation of C-C, C–N, C–O, C–F, C–CF3, and C–S bonds. It is air-, moisture-, and thermally-stable and is highly soluble in a wide range of common organic solvents. Some of its unique features include lower catalyst loadings, shorter reaction time, efficient formation of the active catalytic species and accurate control of ligand: palladium ratio.

Properties of RuPhos Pd G3

Melting point: 188-196°C (decomposition)
storage temp.  under inert gas (nitrogen or Argon) at 2–8 °C
form  Powder
color  white
CAS DataBase Reference 1445085-77-7

Safety information for RuPhos Pd G3

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
H412:Hazardous to the aquatic environment, long-term hazard
Precautionary Statement Codes P273:Avoid release to the environment.
P302+P352:IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for RuPhos Pd G3

InChIKey GYTUQNMMIUJBSP-UHFFFAOYSA-N

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