Tris(3-methoxyphenyl)phosphine
- CAS NO.:29949-84-6
- Empirical Formula: C21H21O3P
- Molecular Weight: 352.36
- MDL number: MFCD00008386
- EINECS: 631-150-0
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-11-17 13:43:30
What is Tris(3-methoxyphenyl)phosphine?
Chemical properties
White to almost white crystalline powder
The Uses of Tris(3-methoxyphenyl)phosphine
suzuki reaction
Synthesis
1-iodo-3-methoxybenzene could be used to synthesize Tri(o-anisole)phosphine (Tris(3-methoxyphenyl)phosphine). Reactions performed using 0.1?mmol NaPH2, 2?mol?% PF6, 11?equiv 1-iodo-3-methoxybenzene, 15?equiv Et3N in 2.0?mL MeCN under blue LED irradiation and N2 atmosphere for 24?h[1].
References
[1]"Photocatalytic Arylation of P4 and PH3: Reaction Development Through Mechanistic Insight." Angewandte Chemie (2021).
Properties of Tris(3-methoxyphenyl)phosphine
Melting point: | 113-115 °C(lit.) |
Boiling point: | 476.3±40.0 °C(Predicted) |
storage temp. | Inert atmosphere,Room Temperature |
form | Crystalline Powder |
color | White to almost white |
InChI | InChI=1S/C21H21O3P/c1-22-16-7-4-10-19(13-16)25(20-11-5-8-17(14-20)23-2)21-12-6-9-18(15-21)24-3/h4-15H,1-3H3 |
CAS DataBase Reference | 29949-84-6(CAS DataBase Reference) |
Safety information for Tris(3-methoxyphenyl)phosphine
Signal word | Warning |
Pictogram(s) |
Exclamation Mark Irritant GHS07 |
GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P304+P340:IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. P405:Store locked up. |
Computed Descriptors for Tris(3-methoxyphenyl)phosphine
InChIKey | CCXTYQMZVYIQRP-UHFFFAOYSA-N |
SMILES | P(C1=CC=CC(OC)=C1)(C1=CC=CC(OC)=C1)C1=CC=CC(OC)=C1 |
New Products
Tubulysin A Tubulysin B Tubulysin D Tubulysin E Tubulysin I (2S,4R)-4-amino-2-methyl-5-phenylpentanoic acid hydrochloride 4-CYANO-TETRAHYDROPYRAN-4-CARBOXYLIC ACID 2H-Pyran, 4-ethynyltetrahydro- 3-METHYLAZETIDIN-3-OL HYDROCHLORIDE Methyl (R)-1-Boc-4,4-difluoropyrrolidine-2-carboxylate Isoxazole, 3-[[[5-(difluoromethoxy)-1-methyl-3-(trifluoromethyl)-1H-pyrazol-4-yl]methyl]thio]-4,5-dihydro-5,5-dimethyl- 4-(Benzyloxy)-3-bromophenylacetic Acid Calcium Sodium Phosphosilicate IH 2-[2-[3(S)-3[2-(7-chloro-2-quinolinyl) ethenyl] phenyl-3- hydroxyl propyl] phenyl]-2-propanol Fuel shell 2-[[(3aR,4S,6R,6aS)-6-Aminotetrahydro-2,2-dimethyl-4H-cyclopenta-1,3-dioxol-4-yl]oxy]ethanol ethanedioate 2-(1-(Mercaptomethyl) cyclopropyl) acetonitrile (1R,2S)-2-(3,4-Difluorophenyl)cyclopropanamine 4-(2-fluoro-4- nitrophenyl) thiomorpholine 2-Methyl-4- nitro Benzoic acid Latanoprostene Bunod Magnesium Trisilicate Lubiprostone Flame Retardant Zinc BorateRelated products of tetrahydrofuran
TRIS(O-METHOXYPHENYL)PHOSPHINE,TRIS(2-METHOXYPHENYL)PHOSPHINE,Tris(o-methoxyphenyl)phosphine,min.98%,Tris(o-methoxyphenyl)phosphine, min. 98%
TRIS(2,4-DIMETHYLPHENYL)PHOSPHINE
TRIS(2,6-DIMETHOXYPHENYL)PHOSPHINE
tris(2-fluorophenyl)phosphane
Tris(4-fluorophenyl)phosphine
Tris(2-carboxyethyl)phosphine hydrochloride
TRIS(4-METHOXYPHENYL)PHOSPHINE
TRIS(2-METHOXYPHENYL)PHOSPHINE OXIDE
You may like
-
Tris(3-methoxyphenyl)phosphine CAS 29949-84-6View Details
29949-84-6 -
Tris(3-methoxyphenyl)phosphine 95% CAS 29949-84-6View Details
29949-84-6 -
Fuel shell 98%View Details
-
4,6-dichloro-2-propylthiopyrimidine-5-amine 145783-15-9 98%View Details
145783-15-9 -
Hydrogen Gas 98%View Details
-
151767-02-1 Montelukast Sodium IP/USP 98%View Details
151767-02-1 -
Valacyclovir Hydrochloride IH 98%View Details
124832-27-5 -
2-[2-[3(S)-3[2-(7-chloro-2-quinolinyl) ethenyl] phenyl-3- hydroxyl propyl] phenyl]-2-propanol 98%View Details
142569-70-8
Statement: All products displayed on this website are only used for non medical purposes such as industrial applications or scientific research, and cannot be used for clinical diagnosis or treatment of humans or animals. They are not medicinal or edible.