TRIS(2,6-DIMETHOXYPHENYL)PHOSPHINE
Synonym(s):DMPP
- CAS NO.：85417-41-0
- Empirical Formula: C24H27O6P
- Molecular Weight: 442.44
- MDL number: MFCD00192558
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-05-11 17:26:00
What is TRIS(2,6-DIMETHOXYPHENYL)PHOSPHINE?
Chemical properties
white to light yellow crystal powde
The Uses of TRIS(2,6-DIMETHOXYPHENYL)PHOSPHINE
Catalyst for:
- Preparation of chiral building blocks via hydroalkynylation reactions or ynolates
- Three-component aza-Morita-Baylis-Hillman reactions (aza-MBH)
- Atom-economic synthesis of nitrogen heterocycles and ynenoates from alkynes
- Oxycylizations of allendiols
- Enantioselective aldol reactions
- Pd-mediated cross-coupling, Pd- and Cu-mediated benzannulation reactions and copper-mediated dimerization reactions
Properties of TRIS(2,6-DIMETHOXYPHENYL)PHOSPHINE
| Melting point: | 145-147 °C(lit.) |
| Boiling point: | 566.4±50.0 °C(Predicted) |
| storage temp. | Sealed in dry,Room Temperature |
| solubility | very faint turbidity in hot Methanol |
| form | Powder |
| color | white to off-white |
| Sensitive | air sensitive |
| CAS DataBase Reference | 85417-41-0 |
Safety information for TRIS(2,6-DIMETHOXYPHENYL)PHOSPHINE
| Signal word | Warning |
| Pictogram(s) |
 Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
| Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P304+P340:IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. P405:Store locked up. |
Computed Descriptors for TRIS(2,6-DIMETHOXYPHENYL)PHOSPHINE
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