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HomeProduct name listTRIS(2,6-DIMETHOXYPHENYL)PHOSPHINE

TRIS(2,6-DIMETHOXYPHENYL)PHOSPHINE

Synonym(s):DMPP

TRIS(2,6-DIMETHOXYPHENYL)PHOSPHINE Structural

What is TRIS(2,6-DIMETHOXYPHENYL)PHOSPHINE?

Chemical properties

white to light yellow crystal powde

The Uses of TRIS(2,6-DIMETHOXYPHENYL)PHOSPHINE

Catalyst for:

  • Preparation of chiral building blocks via hydroalkynylation reactions or ynolates
  • Three-component aza-Morita-Baylis-Hillman reactions (aza-MBH)
  • Atom-economic synthesis of nitrogen heterocycles and ynenoates from alkynes
  • Oxycylizations of allendiols
  • Enantioselective aldol reactions
  • Pd-mediated cross-coupling, Pd- and Cu-mediated benzannulation reactions and copper-mediated dimerization reactions

Properties of TRIS(2,6-DIMETHOXYPHENYL)PHOSPHINE

Melting point: 145-147 °C(lit.)
Boiling point: 566.4±50.0 °C(Predicted)
storage temp.  Sealed in dry,Room Temperature
solubility  very faint turbidity in hot Methanol
form  Powder
color  white to off-white
Sensitive  air sensitive
CAS DataBase Reference 85417-41-0

Safety information for TRIS(2,6-DIMETHOXYPHENYL)PHOSPHINE

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes P261:Avoid breathing dust/fume/gas/mist/vapours/spray.
P304+P340:IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405:Store locked up.

Computed Descriptors for TRIS(2,6-DIMETHOXYPHENYL)PHOSPHINE

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