TRIS(3,5-DIMETHYLPHENYL)PHOSPHINE
Synonym(s):Tri-3,5-xylylphosphine
- CAS NO.：69227-47-0
- Empirical Formula: C24H27P
- Molecular Weight: 346.44
- MDL number: MFCD03094579
- EINECS: 624-162-2
- SAFETY DATA SHEET (SDS)
- Update Date: 2025-01-27 09:38:02
What is TRIS(3,5-DIMETHYLPHENYL)PHOSPHINE?
Chemical properties
white to light yellow crystal powde
The Uses of TRIS(3,5-DIMETHYLPHENYL)PHOSPHINE
Catalyst for:
- Cu / diphosphine-catalyzed asymmetric hydrogenation of heteroaromatic ketones and enones
- Highly selective rhodium-catalyzed hydrogenation reactions
- Classical versus kinetic resolution in preparation of privileged silicon-stereogenic silanaphthalenes
Used for kinetic resolution of donor-functionalized secondary alcohols via Cu-H-catalyzed stereoselective silylation by dehydrogenative Si-O coupling with Si-stereogenic silanes
Used for comparative studies of conformational rigidity of silicon-stereogenic silanes in asymmetric catalysis
Properties of TRIS(3,5-DIMETHYLPHENYL)PHOSPHINE
| Melting point: | 160-165 °C |
| Boiling point: | 474.1±45.0 °C(Predicted) |
| storage temp. | Inert atmosphere,Room Temperature |
| form | crystal |
| color | white |
| EPA Substance Registry System | Phosphine, tris(3,5-dimethylphenyl)- (69227-47-0) |
Safety information for TRIS(3,5-DIMETHYLPHENYL)PHOSPHINE
| Signal word | Warning |
| Pictogram(s) |
 Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H302:Acute toxicity,oral |
| Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P280:Wear protective gloves/protective clothing/eye protection/face protection. P304+P340:IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. P405:Store locked up. |
Computed Descriptors for TRIS(3,5-DIMETHYLPHENYL)PHOSPHINE
New Products
3-Iodophenylacetic acid 3-Pyridineacetonitrile, α-hydroxy- 2-Propanamine, 1-chloro-, hydrochloride (9CI) 3-(hexyloxy)-4-(pyridin-3-yl)-1,2,5-thiadiazole 2-Hexyn-1-ol Dibenzo-18-crown-6 Nickel(II) perchlorate hexahydrate, 98% 4-Bromophenylacetonitrile, 95% 3-Bromo-4-fluoroaniline, 97% Sodium tetraborate decahydrate, 98% Palladium(II) acetate, trimer, Pd 99% 4-Bromo-2-chlorotoluene, 97% N N Dimethylformamide Dimethyl Acetal (Dmf Dma) 2,3-Dichloro Benzoyl Cyanide [Side Chain] Bis(2-Chloroethyl) Amine Hydrochloride L-Glutamic Acid Diethyl Ester Hydrochloride 5-(Difluoromethoxy)-2-Mercaptobenzimidazole 1-Ethyl-3-(3-Dimethylaminopropyl)-Carbodiimide Hydrochloride [EDC Hcl] 1,4-Napthoquinone Bromoiodomethane Sodium Bicarbonate Methylene Dichloride (MDC) Ethyl Acetate Indole-3-Carbinol (I3C)Related products of tetrahydrofuran
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