TRIS(3,5-DIMETHYLPHENYL)PHOSPHINE
Synonym(s):Tri-3,5-xylylphosphine
- CAS NO.:69227-47-0
- Empirical Formula: C24H27P
- Molecular Weight: 346.44
- MDL number: MFCD03094579
- EINECS: 624-162-2
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-12-18 14:08:57
What is TRIS(3,5-DIMETHYLPHENYL)PHOSPHINE?
Chemical properties
white to light yellow crystal powde
The Uses of TRIS(3,5-DIMETHYLPHENYL)PHOSPHINE
Catalyst for:
- Cu / diphosphine-catalyzed asymmetric hydrogenation of heteroaromatic ketones and enones
- Highly selective rhodium-catalyzed hydrogenation reactions
- Classical versus kinetic resolution in preparation of privileged silicon-stereogenic silanaphthalenes
Used for kinetic resolution of donor-functionalized secondary alcohols via Cu-H-catalyzed stereoselective silylation by dehydrogenative Si-O coupling with Si-stereogenic silanes
Used for comparative studies of conformational rigidity of silicon-stereogenic silanes in asymmetric catalysis
Properties of TRIS(3,5-DIMETHYLPHENYL)PHOSPHINE
Melting point: | 160-165 °C |
Boiling point: | 474.1±45.0 °C(Predicted) |
storage temp. | Inert atmosphere,Room Temperature |
form | crystal |
color | white |
EPA Substance Registry System | Phosphine, tris(3,5-dimethylphenyl)- (69227-47-0) |
Safety information for TRIS(3,5-DIMETHYLPHENYL)PHOSPHINE
Signal word | Warning |
Pictogram(s) |
Exclamation Mark Irritant GHS07 |
GHS Hazard Statements |
H302:Acute toxicity,oral |
Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P280:Wear protective gloves/protective clothing/eye protection/face protection. P304+P340:IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. P405:Store locked up. |
Computed Descriptors for TRIS(3,5-DIMETHYLPHENYL)PHOSPHINE
New Products
(S)-3-Aminobutanenitrile hydrochloride 4-Methylphenylacetic acid N-Boc-D-alaninol N-BOC-D/L-ALANINOL Tert-butyl bis(2-chloroethyl)carbamate 3-Morpholino-1-(4-nitrophenyl)-5,6-dihydropyridin- 2(1H)-one Furan-2,5-Dicarboxylic Acid Tropic acid 1-Bromo-3,5-Di-Tert-Butylbenzene S-2-CHLORO PROPIONIC ACID ETHYL ISOCYANOACETATE 2-Bromo-1,3-Bis(Dimethylamino)Trimethinium Hexafluorophosphate 4-IODO BENZOIC ACID 3-NITRO-2-METHYL ANILINE 1-(2,4-DICHLOROPHENYL) ETHANAMINE (2-Hydroxyphenyl)acetonitrile 4-Bromopyrazole 2-(Cyanocyclohexyl)acetic acid 4-methoxy-3,5-dinitropyridine 1-(4-(aminomethyl)benzyl)urea hydrochloride 2-aminopropyl benzoate hydrochloride diethyl 2-(2-((tertbutoxycarbonyl)amino) ethyl)malonate tert-butyl 4- (ureidomethyl)benzylcarbamate Ethyl-2-chloro((4-methoxyphenyl)hydrazono)acetateRelated products of tetrahydrofuran
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TRIS(2,6-DIMETHOXYPHENYL)PHOSPHINE
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tris(2-carboxaldehyde)triphenylphosphine
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