TRIAZAMATE

Synonym(s):Ethyl (3-tert-butyl-1-dimethylcarbamoyl-1H-1,2,4-triazol-5-ylthio)acetate;Ethyl 2-{{1-[(dimethylamino)carbonyl]-3-(1,1-dimethylethyl)-1H-1,2,4-triazol-5-yl}thio}acetate

CAS NO.：112143-82-5
Empirical Formula: C13H22N4O3S
Molecular Weight: 314.4
MDL number: MFCD01632354
SAFETY DATA SHEET (SDS)
Update Date: 2023-04-23 13:52:06

What is TRIAZAMATE?

The Uses of TRIAZAMATE

Triazamate is used for the control of aphids by foliar application on a wide variety of crops. It is suitable for inclusion in integrated pest management because it is minimally toxic to beneficial insects.

The Uses of TRIAZAMATE

Pesticide.

The Uses of TRIAZAMATE

Triazamate is used in controlling unpleasant pests.Used in preparation of Thiazole Manganese Zinc compounds and compounds thereof.

Definition

ChEBI: A triazole insecticide that is 1H-1,2,4-triazole which is substituted at positions 1, 3, and 5 by N,N-dimethylaminocarbonyl, tert-butyl, and (2-ethoxy-2-oxoethyl)sulfanediyl groups, resp ctively.

General Description

Triazamate is a carbamoyl triazole compound, widely used as an insecticide and its mode of action involves the inhibition of cholinesterase in insect pests.

Metabolic pathway

There is only a limited amount of information on the fate of triazamate currently in the public domain. Metabolism in sugar beet and apple has been reported. Animal metabolism studies have been conducted but details are not available. Triazamate is very rapidly metabolised by hydrolysis, decarbamoylation and further metabolism in all biological systems studied (PM).

Degradation

Triazamate is stable under normal conditions and in solution at pH 7 and below. Its DT₅₀ values in buffers are, at pH 5, 7 and 9, 220 days, 49 hours and 1 hour, respectively (PM). Base-catalysed hydrolysis should initially afford triazamate acid (2) by carboxyl ester cleavage (see Scheme 1).
The DTM of triazamate on aqueous photolysis at pH 7 is 301 days (PM)

Properties of TRIAZAMATE

Melting point:	60°
Boiling point:	280°C (rough estimate)
Density	1.2357 (rough estimate)
vapor pressure	1.6 x l0^-4 Pa (25 °C)
refractive index	1.6200 (estimate)
Flash point:	189℃
pka	0.48±0.50(Predicted)
form	neat
Water Solubility	433 mg l^-1(25 °C)
BRN	8422595
EPA Substance Registry System	Triazamate (112143-82-5)

Safety information for TRIAZAMATE

Signal word	Danger
Pictogram(s)	Skull and Crossbones Acute Toxicity GHS06 Environment GHS09
GHS Hazard Statements	H301:Acute toxicity,oral H319:Serious eye damage/eye irritation H330:Acute toxicity,inhalation H400:Hazardous to the aquatic environment, acute hazard
Precautionary Statement Codes	P273:Avoid release to the environment. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.