Tetrabutylammonium perchlorate
Synonym(s):TBAP
- CAS NO.:1923-70-2
- Empirical Formula: C16H36ClNO4
- Molecular Weight: 341.91
- MDL number: MFCD00038722
- EINECS: 217-655-5
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-11-01 18:09:03
What is Tetrabutylammonium perchlorate?
Chemical properties
white powder
The Uses of Tetrabutylammonium perchlorate
Tetrabutylammonium perchlorate is a tetraalkylammonium salt that can be used in phase-transfer catalysis.
The Uses of Tetrabutylammonium perchlorate
Tetrabutylammonium perchlorate is a polarographic supporting electrolyte.
The Uses of Tetrabutylammonium perchlorate
Suitable for use as a polarographic supporting electrolyteTetra-n-butylammonium perchlorate is used as a supporting electrolyte in polarographic measurements.
What are the applications of Application
Tetrabutylammonium perchlorate is a polarographic supporting electrolyte
General Description
Visit our Sensor Applications portal to learn more.
Purification Methods
Crystallise the perchlorate from EtOH ethyl acetate, from n-hexane or diethyl ether/acetone mixture, ethyl acetate or hot CH2Cl2. Dry it in a vacuum at room temperature over P2O5 for 24hours. [Anson et al. J Am Chem Soc 106 4460 1984, Ohst & Kochi J Am Chem Soc 108 2877 1986, Collman et al. J Am Chem Soc 108 2916 1986, Blau & Espenson J Am Chem Soc 108 1962 1986, Gustowski et al. J Am Chem Soc 108 1986, Ikezawa & Kutal J Org Chem 52 3299 1987, Beilstein 4 IV 557.]
Properties of Tetrabutylammonium perchlorate
Melting point: | 211-215 °C |
Density | 1.0387 (rough estimate) |
refractive index | 1.6800 (estimate) |
solubility | acetonitrile: 0.1 g/mL, clear, colorless |
form | Crystalline Powder |
color | White |
Water Solubility | Soluble in acetonitrile and ethanol. Very slightly soluble in water. |
Sensitive | Hygroscopic |
BRN | 3579274 |
Stability: | Stable. Strong oxidizer - contact with combustible material may cause fire. Incompatible with strong reducing agents, combustible materials. Do not heat. |
CAS DataBase Reference | 1923-70-2(CAS DataBase Reference) |
EPA Substance Registry System | 1-Butanaminium, N,N,N-tributyl-, perchlorate (1923-70-2) |
Safety information for Tetrabutylammonium perchlorate
Signal word | Danger |
Pictogram(s) |
Flame Over Circle Oxidizers GHS03 Exclamation Mark Irritant GHS07 |
GHS Hazard Statements |
H272:Oxidising liquids;Oxidising solids H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
Precautionary Statement Codes |
P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking. P302+P352:IF ON SKIN: wash with plenty of soap and water. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for Tetrabutylammonium perchlorate
New Products
4-Fluorophenylacetic acid (S)-3-Aminobutanenitrile hydrochloride 4-Methylphenylacetic acid 5-Aminoimidazole-4-Carbonitrile 4-chloro-3,5-dinitropyridine 2'-Methoxy-biphenyl-2-carboxaldehyde 2-(2-Aminoethyl)isothiourea dihydrobromide, 1-(4-chlorophenyl)propan-1-one 2-Ethyl-4-methyl-1-pentanol DIISOPROPYL MALONATE PENTAFLUOROPHENOL 2-Aminonicotinic acid 6-(4-AMINOPHENYL)-5-METHYL-4,5-DIHYDRO-3(2 H)-PYRDAZINONE β-BUTYROLACTONE 3-OXO-CYCLOBUTANECARBOXYLIC ACID 3-methyl xanthine 1H-Pyrazole-3-carboxylic acid [1,1'-Biphenyl]-4-carboxylic acid (3aR,4R,5R,6aS)-hexahydro-2-oxo-4-[(1E)-3-oxo-4-[3- (trifluoromethyl)phenoxy]-1-buten-1-yl]-2H-cyclopenta[b]furan-5-yl ester 2H-Cyclopenta[b]furan-2,5-diol, hexahydro-4-[(1E,3R)-3-hydroxy-4-[3-(trifluoromethyl)phenoxy]-1- buten-1-yl]-, (3aR,4R,5R,6aS)- 2,5-Dibromopyridine Dimethyl (2-oxo-4-phenylbutyl)phosphonate S-(2-Chloro-3-nitrophenyl) O-ethyl carbonodithioate 1-Methyl-6-oxo-1,6-dihydropyridazine-3-carboxylic acid 2,4-Dichloro-1-[2-nitro-4-(trifluoromethyl)phenoxy]benzeneRelated products of tetrahydrofuran
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