Tetrabutylammonium hexafluorophosphate
- CAS NO.：3109-63-5
- Empirical Formula: C16H36F6NP
- Molecular Weight: 387.43
- MDL number: MFCD00011748
- EINECS: 221-472-6
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-08-11 15:28:25
What is Tetrabutylammonium hexafluorophosphate?
Chemical properties
off-white powder
The Uses of Tetrabutylammonium hexafluorophosphate
Tetrabutylammonium hexafluorophosphate can be used as a supporting electrolyte for the formation of cyclic disulfide moiety of 3,5-diimido-1,2-dithiolane derivatives by S-S coupling of dithioanilides.
The Uses of Tetrabutylammonium hexafluorophosphate
Tetrabutylammonium hexafluorophosphate (TBAPF6) or TBAHP can be used:
- As the supporting electrolyte in cyclic voltammetric studies.
- As a reactant in the synthesis of fluorescent nanofibrous sensing films for detecting nitro-explosive vapors.
General Description
Visit our Sensor Applications portal to learn more.
Purification Methods
Recrystallise it from saturated EtOH/water and dry it for 10hours in a vacuum at 70o. Also recrystallise it three times from absolute EtOH and dry it for 2 days in a drying pistol under a vacuum at boiling toluene temperature [Bedard & Dahl J Am Chem Soc 108 5933 1986]. It is a stable supporting electrolyte in organic solvents [Baiser in Organic Electrochemitry M. Dekker NY p228 1973.]
Properties of Tetrabutylammonium hexafluorophosphate
| Melting point: | 244-246 °C (lit.) |
| Boiling point: | 242-246 °C |
| storage temp. | Inert atmosphere,Room Temperature |
| solubility | acetonitrile: 0.1 g/mL, clear, colorless |
| form | Crystalline Powder and/or Chunks |
| color | White to off-white |
| Sensitive | Hygroscopic |
| BRN | 4056584 |
| InChI | InChI=1S/C16H36N.F6P/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;1-7(2,3,4,5)6/h5-16H2,1-4H3;/q+1;-1 |
| CAS DataBase Reference | 3109-63-5(CAS DataBase Reference) |
| NIST Chemistry Reference | Tetrabutylammonium hexafluorophosphate(3109-63-5) |
| EPA Substance Registry System | 1-Butanaminium, N,N,N-tributyl-, hexafluorophosphate(1-) (3109-63-5) |
Safety information for Tetrabutylammonium hexafluorophosphate
| Signal word | Danger |
| Pictogram(s) |
 Corrosion Corrosives GHS05  Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H302:Acute toxicity,oral H314:Skin corrosion/irritation H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
| Precautionary Statement Codes |
P260:Do not breathe dust/fume/gas/mist/vapours/spray. P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P270:Do not eat, drink or smoke when using this product. P280:Wear protective gloves/protective clothing/eye protection/face protection. P304+P340:IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. P405:Store locked up. P501:Dispose of contents/container to..… |
Computed Descriptors for Tetrabutylammonium hexafluorophosphate
| InChIKey | BKBKEFQIOUYLBC-UHFFFAOYSA-N |
| SMILES | [N+](CCCC)(CCCC)(CCCC)CCCC.[P-](F)(F)(F)(F)(F)F |
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