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HomeProduct name listTetrabutylammonium hydroxide

Tetrabutylammonium hydroxide

  • CAS NO.:2052-49-5
  • Empirical Formula: C16H37NO
  • Molecular Weight: 259.47
  • MDL number: MFCD00009425
  • EINECS: 218-147-6
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-12-18 14:08:57
Tetrabutylammonium hydroxide Structural

What is Tetrabutylammonium hydroxide?

Chemical properties

Aqueous solution.

The Uses of Tetrabutylammonium hydroxide

TBAOH may be used as an ion-pairing reagent in mobile phase preparation for reverse phase ion-pair high performance liquid chromatography during chromium (III) and chromium (VI) determination.

Preparation

Tetrabutylammonium hydroxide was prepared by the ion exchange between gel type strong basic anion exchange resin(OH-) and aqueous solution of tetrabutylammonium bromide.

General Description

The product is 54.0-56.0% solution of tetrabutylammonium hydroxide in H2O. Tetrabutylammonium hydroxide has been synthesized from tetrabutylammonium iodide. TBAOH dissolved in anhydrous isopropyl alcohol is widely employed as titrant for weak acids.

Flammability and Explosibility

Flammable

Properties of Tetrabutylammonium hydroxide

Melting point: 27-30 °C(lit.)
Boiling point: 100 °C
Density  0.995
vapor density  1 (vs air)
vapor pressure  2.3 kPa (@ 20°C)
refractive index  1.4
Flash point: 7°C
storage temp.  Store below +30°C.
solubility  Miscible with organic solvents.
form  Solution
Specific Gravity 0.8586
color  APHA: ≤30
PH Range 14
Odor Odorless
Water Solubility  Soluble in water, methanol.
Sensitive  Air Sensitive/Hygroscopic
BRN  3571228
Exposure limits ACGIH: TWA 200 ppm; STEL 250 ppm (Skin)
OSHA: TWA 200 ppm(260 mg/m3)
NIOSH: IDLH 6000 ppm; TWA 200 ppm(260 mg/m3); STEL 250 ppm(325 mg/m3)
Stability: Volatile
CAS DataBase Reference 2052-49-5(CAS DataBase Reference)
EPA Substance Registry System 1-Butanaminium, N,N,N-tributyl-, hydroxide (2052-49-5)

Safety information for Tetrabutylammonium hydroxide

Signal word Danger
Pictogram(s)
ghs
Corrosion
Corrosives
GHS05
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H314:Skin corrosion/irritation
H317:Sensitisation, Skin
Precautionary Statement Codes P261:Avoid breathing dust/fume/gas/mist/vapours/spray.
P272:Contaminated work clothing should not be allowed out of the workplace.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for Tetrabutylammonium hydroxide

InChIKey VDZOOKBUILJEDG-UHFFFAOYSA-M

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