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HomeProduct name listSamarium oxide

Samarium oxide

Synonym(s):Samaria;Samarium(III) oxide

  • CAS NO.:12060-58-1
  • Empirical Formula: O3Sm2
  • Molecular Weight: 348.72
  • MDL number: MFCD00011237
  • EINECS: 235-043-6
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-10-25 16:21:11
Samarium oxide Structural

What is Samarium oxide?

Chemical properties

light beige crystalline powder

Physical properties

Yellowish-white powder; density 8.347g/cm3; insoluble in water; dissolves readily in mineral acids.

The Uses of Samarium oxide

Samarium sesquioxide is used in optical and infrared absorbing glass to absorb infrared radiation. Also, it is used as a neutron absorber in control rods for nuclear power reactors. The oxide catalyzes dehydration of acyclic primary alcohols to aldehydes and ketones. Another use involves preparation of other samarium salts.

The Uses of Samarium oxide

Samarium(III) oxide is used in optical and infrared absorbing glass to absorb infrared radiation. It finds use as a neutron absorber in nuclear power reactors to control the reaction. It is also used as a catalyst for the dehydration of primary alcohols to aldehydes or ketones. It forms samarium perchlorate when treated with perchloric acid, which is used as a reference material for checking the wavelength scale of a spectrophotometer in the range of 200 to 500 nm.

What are the applications of Application

Samarium(III) oxide is a lanthanide period salt for proteomics research

Preparation

Samarium sesquioxide may be prepared by two methods; (1) thermal decomposition of samarium carbonate, hydroxide, nitrate, oxalate or sulfate:
Sm2(CO3)3 → Sm2O3 + 3CO2
2Sm(OH)3 → Sm2O3 + 3H2O
or (2) by burning the metal in air or oxygen at a temperature above 150°C:
4Sm + 3O2 → 2Sm2O3.

Properties of Samarium oxide

Melting point: 2325 °C
Density  8.35 g/mL at 25 °C(lit.)
refractive index  1.97
storage temp.  no restrictions.
form  nanopowder
color  Violet
Specific Gravity 8.347
PH 8.0 (10g/l, H2O, 25℃)(slurry)
Water Solubility  Insoluble in water.
Crystal Structure Cubic
Merck  14,8347
InChI InChI=1S/3O.2Sm
CAS DataBase Reference 12060-58-1(CAS DataBase Reference)
EPA Substance Registry System Samarium oxide (Sm2O3) (12060-58-1)

Safety information for Samarium oxide

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
Precautionary Statement Codes P280:Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352:IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P332+P313:IF SKIN irritation occurs: Get medical advice/attention.
P337+P313:IF eye irritation persists: Get medical advice/attention.

Computed Descriptors for Samarium oxide

InChIKey PRCWVHVINXAFRG-UHFFFAOYSA-N
SMILES O([Sm]=O)[Sm]=O

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