Samarium oxide
Synonym(s):Samaria;Samarium(III) oxide
- CAS NO.:12060-58-1
- Empirical Formula: O3Sm2
- Molecular Weight: 348.72
- MDL number: MFCD00011237
- EINECS: 235-043-6
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-10-25 16:21:11
What is Samarium oxide?
Chemical properties
light beige crystalline powder
Physical properties
Yellowish-white powder; density 8.347g/cm3; insoluble in water; dissolves readily in mineral acids.
The Uses of Samarium oxide
Samarium sesquioxide is used in optical and infrared absorbing glass to absorb infrared radiation. Also, it is used as a neutron absorber in control rods for nuclear power reactors. The oxide catalyzes dehydration of acyclic primary alcohols to aldehydes and ketones. Another use involves preparation of other samarium salts.
The Uses of Samarium oxide
Samarium(III) oxide is used in optical and infrared absorbing glass to absorb infrared radiation. It finds use as a neutron absorber in nuclear power reactors to control the reaction. It is also used as a catalyst for the dehydration of primary alcohols to aldehydes or ketones. It forms samarium perchlorate when treated with perchloric acid, which is used as a reference material for checking the wavelength scale of a spectrophotometer in the range of 200 to 500 nm.
What are the applications of Application
Samarium(III) oxide is a lanthanide period salt for proteomics research
Preparation
Samarium sesquioxide may be prepared by two methods; (1) thermal decomposition of samarium carbonate, hydroxide, nitrate, oxalate or sulfate:
Sm2(CO3)3 → Sm2O3 + 3CO2
2Sm(OH)3 → Sm2O3 + 3H2O
or (2) by burning the metal in air or oxygen at a temperature above 150°C:
4Sm + 3O2 → 2Sm2O3.
Properties of Samarium oxide
Melting point: | 2325 °C |
Density | 8.35 g/mL at 25 °C(lit.) |
refractive index | 1.97 |
storage temp. | no restrictions. |
form | nanopowder |
color | Violet |
Specific Gravity | 8.347 |
PH | 8.0 (10g/l, H2O, 25℃)(slurry) |
Water Solubility | Insoluble in water. |
Crystal Structure | Cubic |
Merck | 14,8347 |
InChI | InChI=1S/3O.2Sm |
CAS DataBase Reference | 12060-58-1(CAS DataBase Reference) |
EPA Substance Registry System | Samarium oxide (Sm2O3) (12060-58-1) |
Safety information for Samarium oxide
Signal word | Warning |
Pictogram(s) |
Exclamation Mark Irritant GHS07 |
GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation |
Precautionary Statement Codes |
P280:Wear protective gloves/protective clothing/eye protection/face protection. P302+P352:IF ON SKIN: wash with plenty of soap and water. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. P332+P313:IF SKIN irritation occurs: Get medical advice/attention. P337+P313:IF eye irritation persists: Get medical advice/attention. |
Computed Descriptors for Samarium oxide
InChIKey | PRCWVHVINXAFRG-UHFFFAOYSA-N |
SMILES | O([Sm]=O)[Sm]=O |
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