(S)-(-)-N,N-DIMETHYL-1-PHENETHYLAMINE
Synonym(s):(S)-(−)-N,N,α-Trimethylbenzylamine
- CAS NO.：17279-31-1
- Empirical Formula: C10H15N
- Molecular Weight: 149.23
- MDL number: MFCD00056236
- EINECS: 241-310-8
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-06-08 17:06:37
What is (S)-(-)-N,N-DIMETHYL-1-PHENETHYLAMINE?
Chemical properties
clear colorless to yellow liquid
Purification Methods
The amine is mixed with aqueous 10N NaOH and extracted with toluene. The extract is washed with saturated aqueous NaCl, dried over K2CO3, and transferred to fresh K2CO3 until the solution is clear, and is filtered. The filtrate is distilled. If a short column packed with glass helices is used, the yield is reduced but a purer product is obtained. [Ingersoll Org Synth 25 89 1945, Snyder & Brewster J Am Chem Soc 71 291 4165 1949, Cope et al. J Am Chem Soc 71 3931 1949.] The (-)-picrate has m 140-141o from EtOH). The racemate [1126-71-2] has b 88-89o/16mm, 92-94o/30mm, 194-195o/760mm, d4 0.908. [Beilstein 13 III 2392.]
Properties of (S)-(-)-N,N-DIMETHYL-1-PHENETHYLAMINE
| Melting point: | 143°C (estimate) |
| Boiling point: | 81 °C/16 mmHg (lit.) |
| Density | 0.899 g/mL at 25 °C (lit.) |
| refractive index | n |
| Flash point: | 148 °F |
| storage temp. | 2-8°C |
| form | clear liquid |
| pka | 8.88±0.50(Predicted) |
| color | Colorless to Light yellow to Light orange |
| optical activity | [α]20/D 49.2°, c = 1 in methanol |
| BRN | 3196218 |
| CAS DataBase Reference | 17279-31-1(CAS DataBase Reference) |
Safety information for (S)-(-)-N,N-DIMETHYL-1-PHENETHYLAMINE
| Signal word | Warning |
| Pictogram(s) |
 Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H302:Acute toxicity,oral H319:Serious eye damage/eye irritation |
| Precautionary Statement Codes |
P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P270:Do not eat, drink or smoke when using this product. P280:Wear protective gloves/protective clothing/eye protection/face protection. P301+P312:IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. P337+P313:IF eye irritation persists: Get medical advice/attention. |
Computed Descriptors for (S)-(-)-N,N-DIMETHYL-1-PHENETHYLAMINE
New Products
(S)-3-Aminobutanenitrile hydrochloride 4-Methylphenylacetic acid N-Boc-D-alaninol N-BOC-D/L-ALANINOL Tert-butyl bis(2-chloroethyl)carbamate 3-Morpholino-1-(4-nitrophenyl)-5,6-dihydropyridin- 2(1H)-one Furan-2,5-Dicarboxylic Acid Tropic acid 1-Bromo-3,5-Di-Tert-Butylbenzene S-2-CHLORO PROPIONIC ACID ETHYL ISOCYANOACETATE 2-Bromo-1,3-Bis(Dimethylamino)Trimethinium Hexafluorophosphate 4-IODO BENZOIC ACID 3-NITRO-2-METHYL ANILINE 1-(2,4-DICHLOROPHENYL) ETHANAMINE (2-Hydroxyphenyl)acetonitrile 4-Bromopyrazole 2-(Cyanocyclohexyl)acetic acid 4-methoxy-3,5-dinitropyridine 1-(4-(aminomethyl)benzyl)urea hydrochloride 2-aminopropyl benzoate hydrochloride diethyl 2-(2-((tertbutoxycarbonyl)amino) ethyl)malonate tert-butyl 4- (ureidomethyl)benzylcarbamate Ethyl-2-chloro((4-methoxyphenyl)hydrazono)acetateRelated products of tetrahydrofuran
![1-[BIS-(4-FLUOROPHENYL)-METHYL]-PIPERIDINE](https://img.chemicalbook.in/CAS/GIF/252644-60-3.gif)
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