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HomeProduct name listrac-Ethylenebis(4,5,6,7-tetrahydro-1-indenyl)]zirconium dichloride

rac-Ethylenebis(4,5,6,7-tetrahydro-1-indenyl)]zirconium dichloride

Synonym(s):Dichloro[rel-(7aR,7′aR)-1,2-ethanediylbis[(1,2,3,3a,7a-η)-4,5,6,7-tetrahydro-1H-inden-1-ylidene]]zirconium

rac-Ethylenebis(4,5,6,7-tetrahydro-1-indenyl)]zirconium dichloride Structural

What is rac-Ethylenebis(4,5,6,7-tetrahydro-1-indenyl)]zirconium dichloride?

Chemical properties

White to pale yellow powder,it can carry out catalytic reaction.

The Uses of rac-Ethylenebis(4,5,6,7-tetrahydro-1-indenyl)]zirconium dichloride

Rac-Ethylenebis(tetrahydroindenyl)zirconium Dichloride is a catalyst for enantioselective methylalumination of monosubstituted alkenes.The Kaminsky catalyst with co-catalyst methylaluminoxane (MAO) is a type of Ziegler-Natta catalyst, showing extremely high activity for polymerization of olefins such as ethylene, propylene, and styrene.

The Uses of rac-Ethylenebis(4,5,6,7-tetrahydro-1-indenyl)]zirconium dichloride

Catalyst for:
Regiochemistry in Negishi carboaluminations
Polymerization of olefins
Diastereoselective intramolecular olefin alkylations
Asymmetric carbomagnesiation
Reduction of esters to alcohols
Enantioselective synthesis of allylic amines

Properties of rac-Ethylenebis(4,5,6,7-tetrahydro-1-indenyl)]zirconium dichloride

Melting point: 267-271 °C(lit.)
form  Powder
color  white to pale yellow
Sensitive  moisture sensitive

Safety information for rac-Ethylenebis(4,5,6,7-tetrahydro-1-indenyl)]zirconium dichloride

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes P261:Avoid breathing dust/fume/gas/mist/vapours/spray.
P264:Wash hands thoroughly after handling.
P264:Wash skin thouroughly after handling.
P271:Use only outdoors or in a well-ventilated area.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352:IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for rac-Ethylenebis(4,5,6,7-tetrahydro-1-indenyl)]zirconium dichloride

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