(R)-(-)-1,2,3,4-Tetrahydro-1-naphthylamine
Synonym(s):(R)-(−)-1-AminoTetralin;(R)-(−)-1-Aminotetraline;(R)-1,2,3,4-Tetrahydro-1-naphthylamine
- CAS NO.:23357-46-2
- Empirical Formula: C10H13N
- Molecular Weight: 147.22
- MDL number: MFCD00671629
- EINECS: 628-771-4
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-06-26 08:28:20
What is (R)-(-)-1,2,3,4-Tetrahydro-1-naphthylamine?
The Uses of (R)-(-)-1,2,3,4-Tetrahydro-1-naphthylamine
(R)-(-)-1,2,3,4-Tetrahydro-1-naphthylamine is a important organic intermediate. It can be used in agrochemical, pharmaceutical and dyestuff field. Chiral amines play an important role in stereoselective organic synthesis. They are used directly as resolving agents, building blocks or chiral auxiliaries.
Synthesis
(R)-1-Amino-1,2,3,4-tetrahydronaphthalene is a contactor that can be synthesized by the reaction of an enantiomerically pure amine with a primary oxidant.
Properties of (R)-(-)-1,2,3,4-Tetrahydro-1-naphthylamine
Melting point: | 116-119 °C |
Boiling point: | 118-120 °C/10 mbar |
Density | 1.002 g/mL at 25 °C |
refractive index | 1.565 |
Flash point: | >110°C |
storage temp. | Keep in dark place,Inert atmosphere,Room temperature |
form | clear liquid |
pka | 9.39±0.20(Predicted) |
color | Colorless to Light yellow to Light orange |
Water Solubility | Soluble in water (6.91g/L at 25°C). |
Sensitive | Air Sensitive |
BRN | 4231302 |
InChI | InChI=1S/C10H13N/c11-10-7-3-5-8-4-1-2-6-9(8)10/h1-2,4,6,10H,3,5,7,11H2/t10-/m1/s1 |
CAS DataBase Reference | 23357-46-2(CAS DataBase Reference) |
Safety information for (R)-(-)-1,2,3,4-Tetrahydro-1-naphthylamine
Signal word | Danger |
Pictogram(s) |
Corrosion Corrosives GHS05 Exclamation Mark Irritant GHS07 |
GHS Hazard Statements |
H302:Acute toxicity,oral H314:Skin corrosion/irritation H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation H412:Hazardous to the aquatic environment, long-term hazard |
Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P273:Avoid release to the environment. P280:Wear protective gloves/protective clothing/eye protection/face protection. P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower. P304+P340:IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. P405:Store locked up. |
Computed Descriptors for (R)-(-)-1,2,3,4-Tetrahydro-1-naphthylamine
InChIKey | JRZGPXSSNPTNMA-SNVBAGLBSA-N |
SMILES | [C@H]1(N)C2=C(C=CC=C2)CCC1 |
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