PSEUDOJERVINE
- CAS NO.:36069-05-3
- Empirical Formula: C33H49NO8
- Molecular Weight: 587.749
- MDL number: MFCD01716648
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-11-09 19:38:33
What is PSEUDOJERVINE?
Description
This alkaloid has been found in both Veratrum album and V. viride Ait. It crystallizes from EtOH in hexagonal tablets and has [α]20D - 139° (CHC13). The hydrochloride dihydrate has m.p. 254-6°C (dry, dec.); the sulphate is also crystalline but the aurichloride is amorphous. Poethke has shown that the alkaloid is a secondary base, gives a nitro so derivative, m.p. 261°C, and contains five replaceable hydrogen atoms. On boiling with dilute HCl it is hydrolyzed to (+)- glucose and isojervine, an isomer of jervine. This latter base crystallizes with solvent, e.g. the CHC13 adduct softens at 135-1500 C; the crystallizate with EtOH has m.p. 114-6°C (dec.) and that with Me2CO has m.p. 110-4°C; [α]20D - 32° (EtOH).
Definition
ChEBI: Pseudojervine is a steroid saponin.
References
Wright, Luff., J. Chem. Soc., 35,405,421 (1879)
Salzberger., Arch. Pharm., 228,462 (1890)
Poethke., ibid, 275,357,571 (1937)
Poethke., ibid, 276, 170 (1938)
Jacobs, Craig.,J. Biol. Chem., 155,564 (1944)
Properties of PSEUDOJERVINE
Melting point: | 300-301° (dec) |
Boiling point: | 643.44°C (rough estimate) |
alpha | D25 -133° (c = 0.48 in 1:3 ethanol-chloroform) |
Density | 1.1485 (rough estimate) |
refractive index | 1.5960 (estimate) |
pka | 12.91±0.70(Predicted) |
Safety information for PSEUDOJERVINE
Computed Descriptors for PSEUDOJERVINE
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ALUMINIUM IODIDE 100 GM BUFFER CAPSULE PH 7.0 - 10 CAP BUFFER SOLUTION PH 9.5 (BORATE) EZEE BLUE GEL STAINER BORAX CARMINE (GRENACHERS ALCOHOLIC) POTASSIUM IODATE - IODIDE SOLN 0.1 N Dabigatran Acyl-O3-D-Glucuronide Trifluoroacetic Acid Salt Isofolic Acid Dabigatran 2-O-acylglucuronide metabolite Dabigatran Acyl-?-D- glucuronide Trifluroacetic Acid Erythromycin EP Impurity A Desloratidine Related Compound ARelated products of tetrahydrofuran
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