POTASSIUM TRI-SEC-BUTYLBOROHYDRIDE

Synonym(s):Potassium tri-sec-butylborohydride solution

CAS NO.：54575-49-4
Empirical Formula: C12H25BK
Molecular Weight: 219.24
MDL number: MFCD00009324
EINECS: 259-241-7
SAFETY DATA SHEET (SDS)
Update Date: 2023-10-21 09:24:07

POTASSIUM TRI-SEC-BUTYLBOROHYDRIDE Structural

What is POTASSIUM TRI-SEC-BUTYLBOROHYDRIDE?

Description

Potassium tri-sec-butylborohydride [54575- 49-4] solution in tetrahydrofuran (THF) is sold as K-Selectride (Aldrich). These compounds may be used for highly stereoselective reductions, e.g., of ketones . Chemical rearrangements induced by potassium hydride are important in organic chemistry. Furthermore, in combination with other reagents potassium hydride acts as a catalyst in the polymerization of alkenes and dienes.

Chemical properties

clear slightly yellow solution

The Uses of POTASSIUM TRI-SEC-BUTYLBOROHYDRIDE

Reducing reagent. Reactant for: Preparation of a PCP-pincer palladium hydride-K-Selectride complex. Formation of P-H, P-C, and C-H bonds by hydride attack. Stereoselective conjugate hydride reduction reactions.

The Uses of POTASSIUM TRI-SEC-BUTYLBOROHYDRIDE

Mild reducing agents in organic synthesis.

The Uses of POTASSIUM TRI-SEC-BUTYLBOROHYDRIDE

Reducing reagent

Reactant for:

Preparation of a PCP-pincer palladium hydride-K-Selectride complex
Formation of P-H, P-C, and C-H bonds by hydride attack
Stereoselective conjugate hydride reduction reactions

What are the applications of Application

Potassium tri-sec-butylborohydride solution is a stereospecific reducing agent for ketones

Properties of POTASSIUM TRI-SEC-BUTYLBOROHYDRIDE

Density	0.913 g/mL at 25 °C
Flash point:	1 °F
storage temp.	Flammables + water-Freezer (-20°C)e area
form	Solution
color	Clear slightly yellow
Sensitive	moisture sensitive
EPA Substance Registry System	Borate(1-), hydrotris(1-methylpropyl)-, potassium, (T-4)- (54575-49-4)

Safety information for POTASSIUM TRI-SEC-BUTYLBOROHYDRIDE

Signal word	Danger
Pictogram(s)	Flame Flammables GHS02 Corrosion Corrosives GHS05 Exclamation Mark Irritant GHS07 Health Hazard GHS08
GHS Hazard Statements	H225:Flammable liquids H260:Substances And Mixtures Which, In Contact With Water,Emit Flammable Gases H314:Skin corrosion/irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation H351:Carcinogenicity
Precautionary Statement Codes	P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking. P280:Wear protective gloves/protective clothing/eye protection/face protection. P231+P232:Handle under inert gas. Protect from moisture. P370+P378:In case of fire: Use … for extinction. P402+P404:Store in a dry place. Store in a closed container. P403+P235:Store in a well-ventilated place. Keep cool.