Potassium osmate(VI) dihydrate
Synonym(s):Potassium osmate dihydrate
- CAS NO.:10022-66-9
- Empirical Formula: H2KO5Os-
- Molecular Weight: 311.34
- MDL number: MFCD00149919
- EINECS: 628-964-3
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-10-31 09:19:22
What is Potassium osmate(VI) dihydrate?
Chemical properties
violet crystalline powder
The Uses of Potassium osmate(VI) dihydrate
Determination of nitrogenous matter in water.
The Uses of Potassium osmate(VI) dihydrate
Potassium osmium(VI) oxide dihydrate acts as a catalyst for the oxidative cleavage of olefins to ketones and carboxylic acids. It is employed in an intramolecular amidohydroxylation of carbamoyloxytethered olefins providing hydroxy oxazolidinones. It is also used as a reagent in the synthesis of amphidinolide B, which shows potent antitumor activity against human solid and blood tumor cells.
What are the applications of Application
Potassium osmate(VI) dihydrate is a reagent used in the oxidative cleavage of carboxylic acids and olefins to ketones
Reactivity Profile
catalyst for oxidative cleavage; oxidation reagent; used in dihydroxylation and aminohydroxylation reactions.
Hazard
Toxic by ingestion and inhalation.
storage
incompatible with strong oxidizing reagents. Toxic if inhaled. May cause respiratory tract irritation. Toxic if absorbed through the skin. Toxic if swallowed.
Structure and conformation
The complex anion is octahedral. Like related d2 dioxo complexes, the oxo ligands are trans. The Os=O and Os-OH distances are 1.75(2) and 1.99(2) Å, respectively. It is a relatively rare example of a metal oxo complex that obeys the 18e rule.
Properties of Potassium osmate(VI) dihydrate
storage temp. | Store below +30°C. |
form | Powder |
color | White |
Water Solubility | Soluble in water. Slowly decomposes in aqueous solution forming the tetroxide. Insoluble in alcohol, etherSoluble in water. Insoluble in alcohol and ether. |
Sensitive | Hygroscopic |
Stability: | hygroscopic |
InChI | InChI=1S/K.H2O.4O.Os/h;1H2;;;;;/q+1;;;;;;-2 |
Safety information for Potassium osmate(VI) dihydrate
Signal word | Danger |
Pictogram(s) |
Skull and Crossbones Acute Toxicity GHS06 |
Precautionary Statement Codes |
P280:Wear protective gloves/protective clothing/eye protection/face protection. |
Computed Descriptors for Potassium osmate(VI) dihydrate
InChIKey | DGODWNOPHMXOTR-UHFFFAOYSA-N |
SMILES | [Os-2](=O)(=O)(=O)=O.[K+].O |
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