N,N-Dimethylacrylamide
Synonym(s):2-Propenamide
- CAS NO.:2680-03-7
- Empirical Formula: C5H9NO
- Molecular Weight: 99.13
- MDL number: MFCD00008626
- EINECS: 220-237-5
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-11-04 13:44:46
What is N,N-Dimethylacrylamide?
Description
N, N-dimethylacrylamide (DMAA) is an easily polymerized, nonionic monomer. The high reactivity and low initiation temperature of DMAA makes it appropriate for copolymerization. Copolymers of DMAA with N, N-dimethyl-N, and N-diallyl ammonium chloride (DMDAAC) can be used as polymeric flocculants for water treatment. The unique structure of DMAA shows amelioration in hydrogels for specific applications. DMAA, along with other hydrogels, has a three-dimensional network structure that is capable of retaining water. In addition, DMAA hydrogel can be applied to remove toxic metal ions from wastewater because of its characteristic properties such as chemical stability and high adsorption capacity. DMAA can also be used for flocculation due to its ability to augment the molecular weight of the copolymers[1].
Chemical properties
Colorless liquid
The Uses of N,N-Dimethylacrylamide
N,N-Dimethylacrylamide is a useful monomer for synthetic fibers and plastics. It is also used in the synthesis of photoresponsive polymers and copolymers by grafting polysiloxane on the side chain of DMA by homopolymerization or grafting cellulose to form cellulose polymers and copolymerization of methyl methacrylate with DMA or copolymerization of DMA with styrene and butadiene.
The Uses of N,N-Dimethylacrylamide
DMA is used in the synthesis of photoresponsive polymers. It is used in the synthesis of copolymers by
grafting polysiloxane on the side chain of DMA by homopolymerization or
grafting cellulose to form cellulose polymers and
copolymerization of methyl methacrylate with DMA or
copolymerization of DMA with styrene and butadiene
Synthesis Reference(s)
Journal of the American Chemical Society, 79, p. 875, 1957 DOI: 10.1021/ja01561a024
General Description
N,N-Dimethylacrylamide (DMA) is a nonionic acrylic monomer that can make swellable polymeric particles.
References
[1] Ayatzhan Akhmetzhan. “A Short Review on the N,N-Dimethylacrylamide-Based Hydrogels.” Gels 7 4 (2021).
Properties of N,N-Dimethylacrylamide
Melting point: | 100 °C |
Boiling point: | 80-81 °C/20 mmHg (lit.) |
Density | 0.962 g/mL at 25 °C (lit.) |
vapor pressure | 65Pa at 20℃ |
refractive index | n |
Flash point: | 161 °F |
storage temp. | 2-8°C(protect from light) |
form | Liquid |
pka | -0.77±0.70(Predicted) |
color | Colorless to Light yellow |
Water Solubility | Slightly soluble in water (1.000 g/L at 20°C). |
FreezingPoint | -40℃ |
Sensitive | Light Sensitive |
BRN | 1742219 |
Exposure limits | ACGIH: TWA 5 mg/m3 NIOSH: TWA 5 mg/m3 |
CAS DataBase Reference | 2680-03-7(CAS DataBase Reference) |
NIST Chemistry Reference | 2-propenamide, N,N-dimethyl(2680-03-7) |
EPA Substance Registry System | 2-Propenamide, N,N-dimethyl- (2680-03-7) |
Safety information for N,N-Dimethylacrylamide
Signal word | Danger |
Pictogram(s) |
Corrosion Corrosives GHS05 Skull and Crossbones Acute Toxicity GHS06 |
GHS Hazard Statements |
H318:Serious eye damage/eye irritation |
Precautionary Statement Codes |
P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P270:Do not eat, drink or smoke when using this product. P280:Wear protective gloves/protective clothing/eye protection/face protection. P301+P310:IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for N,N-Dimethylacrylamide
New Products
4-Aminotetrahydropyran-4-carbonitrile Hydrochloride (R)-3-Aminobutanenitrile Hydrochloride 4-AMINO-TETRAHYDRO-PYRAN-4-CARBOXYLIC ACID HCL 4-(Dimethylamino)tetrahydro-2H-pyran-4-carbonitrile 3-((Dimethylamino)methyl)-5-methylhexan-2-one oxalate 1,4-Dioxa-8-azaspiro[4.5]decane 5-Bromo-2-nitropyridine Nimesulide BP Aceclofenac IP/BP/EP Diclofenac Sodium IP/BP/EP/USP Mefenamic Acid IP/BP/EP/USP Ornidazole IP Diclofenac Potassium SODIUM AAS SOLUTION ZINC AAS SOLUTION BUFFER SOLUTION PH 10.0(BORATE) GOOCH CRUCIBLE SINTERED AQUANIL 5 BERYLLIUM AAS SOLUTION 2-Bromo-1-(bromomethyl)-3-chloro-5-nitrobenzene 2-Bromo-3-nitroaniline N-(3-Hydroxypropyl)-N-methylacetamide 3-Bromo-6-chloropyridazine 4-ethyl-3-nitrobenzoic acidRelated products of tetrahydrofuran
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