N-Phenylbenzylamine
Synonym(s):N-Phenylbenzylamine;N-Benzylaniline;N-Phenylbenzylamine
- CAS NO.：103-32-2
- Empirical Formula: C13H13N
- Molecular Weight: 183.25
- MDL number: MFCD00003018
- EINECS: 203-100-4
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-08-04 20:11:12
What is N-Phenylbenzylamine?
Chemical properties
colorless to yellow-beige crystalline powder
The Uses of N-Phenylbenzylamine
N-Benzylaniline is a major metabolite of the antihistaminic Antazoline and other N-substituted benzylanilines.
The Uses of N-Phenylbenzylamine
N-Benzylaniline was used in the separation of tervalent gallium, indium and thallium by solvent extraction method.
Synthesis Reference(s)
Chemistry Letters, 8, p. 45, 1979
Organic Syntheses, Coll. Vol. 1, p. 102, 1941
Tetrahedron Letters, 19, p. 4987, 1978 DOI: 10.1016/S0040-4039(01)85789-0
General Description
The electropolymerisation of N-benzylaniline at transparent Indium Tin Oxide glass electrodes has been investigated by UV-visible spectroelectrochemistry. N-Benzylaniline on electrochemical oxidation in aqueous sulfuric acid solution produces an adherent conducting polymer film at the platinum electrode.
Purification Methods
Crystallise the amine from pet ether (b 60-80o) (ca 0.5mL/g). The picrate has m 113o (from Et2O). [Beilstein 12 H 1023, 12 I 449, 12 II 548, 12 III 2215, 12 IV 2172.]
Properties of N-Phenylbenzylamine
| Melting point: | 35-38 °C (lit.) |
| Boiling point: | 306-307 °C (lit.) |
| Density | 1.061 g/mL at 25 °C (lit.) |
| refractive index | n |
| Flash point: | 217 °F |
| storage temp. | Store below +30°C. |
| solubility | alcohol: soluble |
| form | Crystalline Powder or Low Melting Mass |
| pka | 3.89±0.10(Predicted) |
| Specific Gravity | 1.061 |
| color | Colorless to yellow-beige |
| Water Solubility | INSOLUBLE |
| Merck | 14,1126 |
| CAS DataBase Reference | 103-32-2(CAS DataBase Reference) |
| NIST Chemistry Reference | Benzenemethanamine, N-phenyl-(103-32-2) |
| EPA Substance Registry System | Benzenemethanamine, N-phenyl- (103-32-2) |
Safety information for N-Phenylbenzylamine
| Signal word | Warning |
| Pictogram(s) |
 Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
| Precautionary Statement Codes |
P280:Wear protective gloves/protective clothing/eye protection/face protection. P302+P352:IF ON SKIN: wash with plenty of soap and water. |
Computed Descriptors for N-Phenylbenzylamine
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