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HomeProduct name listMethyl Orange

Methyl Orange

Synonym(s):4-[4-(Dimethylamino)phenylazo]benzenesulfonic acid sodium salt;4-Dimethylaminoazobenzene-4′-sulfonic acid sodium salt, Gold orange, Helianthine, Orange III;Acid Orange 52;Helianthin;Orange III

  • CAS NO.:547-58-0
  • Empirical Formula: C14H14N3NaO3S
  • Molecular Weight: 327.33
  • MDL number: MFCD00007502
  • EINECS: 208-925-3
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-07-31 17:39:26
Methyl Orange Structural

What is Methyl Orange?

Chemical properties

Orange-yellow powder. Soluble in hotwater; insoluble in alcohol.

The Uses of Methyl Orange

Methyl orange is a pH indicator frequently used in titrations, also used for histological microscopy.

The Uses of Methyl Orange

As indicator in 0.1% aqueous solution. pH: 3.1 red, 4.4 yellow. Employed for titrating most mineral acids, strong bases, estimating alkalinity of waters; useless for organic acids. In dyeing and printing of textiles.

What are the applications of Application

Methyl orange is a pH indicator dye for titrations

Definition

An acid–base indicator that is red in solutions below a pH of 3 and yellow above a pH of 4.4. As the transition range is clearly on the acid side, methyl orange is suitable for the titration of an acid with a moderately weak base, such as sodium carbonate.

Definition

methyl orange: An organic dyeused as an acid–base indicator. Itchanges from red below pH 3.1 toyellow above pH 4.4 (at 25°C) and isused for titrations involving weakbases.

Preparation

4-Aminobenzenesulfonic acid diazo, and N,N-dimethylaniline coupling.

General Description

Orange powder.

Air & Water Reactions

Azo dyes can be explosive when suspended in air at specific concentrations. Insoluble in water.

Reactivity Profile

Methyl Orange is an azo compound. Azo, diazo, azido compounds can detonate. This applies in particular to organic azides that have been sensitized by the addition of metal salts or strong acids. Toxic gases are formed by mixing materials of this class with acids, aldehydes, amides, carbamates, cyanides, inorganic fluorides, halogenated organics, isocyanates, ketones, metals, nitrides, peroxides, phenols, epoxides, acyl halides, and strong oxidizing or reducing agents. Flammable gases are formed by mixing materials in this group with alkali metals. Explosive combination can occur with strong oxidizing agents, metal salts, peroxides, and sulfides.

Purification Methods

Recrystallise it twice from hot water, then wash it with a little EtOH followed by diethyl ether. It is an indicator: pH 3.1 (red) and pH 4.4 (yellow). [Beilstein 16 IV 510.]

Properties and Applications

orange. The strong sulfuric acid for green light yellow, diluted into red orange. The dye solution to join strong hydrochloric acid for orange red; Add thick sodium hydroxide solution for green light yellow.

Standard Light Fastness Soaping Persperation Fastness Oxygen bleaching Fastness to seawater
Fading Stain Fading Stain Fading Stain
ISO
AATCC

Properties of Methyl Orange

Melting point: 300 °C
Density  0.987 g/mL at 25 °C
Flash point: 37 °C
storage temp.  Store at +5°C to +30°C.
solubility  5g/l
form  Powder/Solid
Colour Index  13025
pka 3.4(at 25℃)
color  Yellow-Orange
Specific Gravity 0.987
PH 6.5 (5g/l, H2O, 20℃)
Odor Odorless
PH Range 3.1(Red)-4.4(Orange)
Water Solubility  Soluble in ethanol. Partially soluble in hot water. Slightly soluble in cold water and pyrimidine. Insoluble in ether and alcohol.
λmax 507nm, 522nm, 464nm
Merck  14,6105
BRN  4732884
Stability: Stable. Incompatible with strong oxidizing agents.
Biological Applications Detecting microorganisms; treating dermatological diseases,vaginal affections; dental materials; wound dressing materials
Major Application Liquid crystals, thin films, sensors, sol-gel matrix, waveguides, host-guest chemistry, display device, corrosion inhibitor, glass coatings, paints, wound dressing materials, pharmaceuticals, dental materials, measuring nucleic acid
CAS DataBase Reference 547-58-0
EPA Substance Registry System Methyl orange (547-58-0)

Safety information for Methyl Orange

Signal word Danger
Pictogram(s)
ghs
Skull and Crossbones
Acute Toxicity
GHS06
GHS Hazard Statements H301:Acute toxicity,oral
Precautionary Statement Codes P264:Wash hands thoroughly after handling.
P264:Wash skin thouroughly after handling.
P270:Do not eat, drink or smoke when using this product.
P301+P310:IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P405:Store locked up.
P501:Dispose of contents/container to..…

Computed Descriptors for Methyl Orange

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