Lithium triisobutylhydroborate
Synonym(s):Lithium tri-sec-butylborohydride solution
- CAS NO.：38721-52-7
- Empirical Formula: C12H28B.Li
- Molecular Weight: 190.1
- MDL number: MFCD00011708
- EINECS: 254-101-1
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-11-14 14:09:35
What is Lithium triisobutylhydroborate?
Physical properties
clear colourless solution
The Uses of Lithium triisobutylhydroborate
Lithium triisobutylhydroborate is used as a reducing agent. Reagent for: Enantioselective synthesis of a-amino acids via reduction of N-tert-butanesulfinyl ketimine esters. Diastereoselective reduction reactions. Hydride reduction of the Danishefsky pyranones. Asymmetric reductive aldol reaction of enones with a-alkoxy aldehydes. Synthesis of alkanols by carbonylation reactions.
The Uses of Lithium triisobutylhydroborate
L-Selectride Solution is a reducing agent which is used in the preparation of oxygen heterocycles. Used also as a reactant in the synthesis of novel bicicyclo[3.1.0]hexane analags which may prove useful in the treatment of depression.
Properties of Lithium triisobutylhydroborate
| Density | 0.89 g/mL at 25 °C |
| Flash point: | 1 °F |
| storage temp. | Flammables area |
| solubility | Miscible with tetrahydrofuran. |
| form | Liquid |
| color | Colorless to yellow |
| Water Solubility | reacts |
| Sensitive | Moisture Sensitive |
| BRN | 4007327 |
| CAS DataBase Reference | 38721-52-7(CAS DataBase Reference) |
| EPA Substance Registry System | Borate(1-), hydrotris(1-methylpropyl)-, lithium, (T-4)- (38721-52-7) |
Safety information for Lithium triisobutylhydroborate
| Signal word | Danger |
| Pictogram(s) |
 Flame Flammables GHS02  Corrosion Corrosives GHS05  Exclamation Mark Irritant GHS07  Health Hazard GHS08 |
| GHS Hazard Statements |
H225:Flammable liquids H250:Pyrophoric liquids; Pyrorophoric solids H260:Substances And Mixtures Which, In Contact With Water,Emit Flammable Gases H314:Skin corrosion/irritation H318:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation H351:Carcinogenicity |
| Precautionary Statement Codes |
P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking. P280:Wear protective gloves/protective clothing/eye protection/face protection. P231+P232:Handle under inert gas. Protect from moisture. P310:Immediately call a POISON CENTER or doctor/physician. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. P370+P378:In case of fire: Use … for extinction. P422:Store contents under … P402+P404:Store in a dry place. Store in a closed container. |
Computed Descriptors for Lithium triisobutylhydroborate
| InChIKey | ACJKNTZKEFMEAK-UHFFFAOYSA-N |
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product: L-Selectride (1.0 M in THF) 38721-52-7
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