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HomeProduct name listEthyltriphenylphosphonium iodide

Ethyltriphenylphosphonium iodide

Synonym(s):ETPPI;Phenylphosphonium ethyl iodide

  • CAS NO.:4736-60-1
  • Empirical Formula: C20H20IP
  • Molecular Weight: 418.251031
  • MDL number: MFCD00040352
  • EINECS: 225-245-2
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-08-12 17:17:06
Ethyltriphenylphosphonium iodide Structural

What is Ethyltriphenylphosphonium iodide?

Chemical properties

Ethyltriphenylphosphonium iodide is white to slightly yellowish crystalline powder

The Uses of Ethyltriphenylphosphonium iodide

Ethyltriphenylphosphonium iodide is used as a Wittig reagent and phase transfer catalyst in organic synthesis. It can also be used in asymmetric hydrogenation and to make Bismuth(III) polynuclear complexes.

The Uses of Ethyltriphenylphosphonium iodide

Ethyltriphenylphosphonium iodide is involved in synthesis of diarylmethine derivatives, phosphonium salts, and bismuth(III) polynuclear halide complexes, asymmetric hydrogenation.

Flammability and Explosibility

Not classified

Synthesis

(1) adding triphenyl phosphine to an organic solvent, adding ethyl chloride in a dropwise manner, heating to a temperature of 120-160℃ after the adding, adjusting the reaction pressure to 8-12 kg/cm2, and carrying out a thermal insulation reaction for 30-40 h; (2) after completing the thermal insulation reaction, cooling to a room temperature, reducing the pressure to a normal pressure, and carrying out centrifugation on the material obtained after the reaction; and (3) drying the centrifugal precipitate so as to obtain the ethyl triphenyl phosphonium chloride.

Properties of Ethyltriphenylphosphonium iodide

Melting point: 164-168 °C(lit.)
Boiling point: 337 °C
Density  1.500
vapor pressure  0Pa at 25℃
Flash point: 226 °C
storage temp.  Keep in dark place,Inert atmosphere,Room temperature
solubility  Acetone, Chloroform, Dichloromethane, Methanol
form  Powder
color  Yellow
Water Solubility  slightly soluble
Sensitive  Light Sensitive & Hygroscopic
BRN  3659323
CAS DataBase Reference 4736-60-1(CAS DataBase Reference)
EPA Substance Registry System Phosphonium, ethyltriphenyl-, iodide (4736-60-1)

Safety information for Ethyltriphenylphosphonium iodide

Signal word Danger
Pictogram(s)
ghs
Skull and Crossbones
Acute Toxicity
GHS06
GHS Hazard Statements H301:Acute toxicity,oral
H319:Serious eye damage/eye irritation
Precautionary Statement Codes P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for Ethyltriphenylphosphonium iodide

InChIKey SLAFUPJSGFVWPP-UHFFFAOYSA-M

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