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HomeProduct name listEthyl carbazate

Ethyl carbazate

Synonym(s):Hydrazinocarboxylic acid ethyl ester

  • CAS NO.:4114-31-2
  • Empirical Formula: C3H8N2O2
  • Molecular Weight: 104.11
  • MDL number: MFCD00007595
  • EINECS: 223-903-3
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-08-21 22:41:43
Ethyl carbazate Structural

What is Ethyl carbazate?

Chemical properties

Off-white crystals.

The Uses of Ethyl carbazate

Prepare 4-phenylurazole from ethyl carbazate and then oxidize the urazole with gaseous dinitrogen tetroxide to yield 4-phenyl-1,2,4-tri- azoline-3,5-dione la. Modification of the ethyl carbazate procedure in which analytically pure monoalkylhydrazine hydrochlorides were isolated in greater than 90% yield, starting from a ketone or aldehyde. Treatment of primary amines is with chloroamine or hydroxylamine-0-sulfonic acid and the condensation of a carbonyl compound with ethyl carbazate. The FeCl 3 -catalyzed reaction of ethyl carbazate (2 b) proceeded readily to give β-hydroxyester 3 b in better yield. A new one-pot neat synthesis of some 5-aryl-2,4-dihydro-3H-1,2,4-triazol-3-ones through cyclocondensation of ethyl carbazate with aryl nitriles catalyzed by DMAP as an efficient and basic nucleophilic catalyst is described.

The Uses of Ethyl carbazate

Synthetic intermediate.

Hazard

Irritant.

Purification Methods

Fractionate the carbazate using a Vigreux column (p 11) until the distillate crystallises [Allen & Bell Org Synth Coll Vol III 404 1955, Beilstein 3 IV 174].

Properties of Ethyl carbazate

Melting point: 44-47 °C (lit.)
Boiling point: 108-110 °C/22 mmHg (lit.)
Density  1.2719 (rough estimate)
refractive index  1.4715 (estimate)
Flash point: 187 °F
storage temp.  Keep in dark place,Inert atmosphere,Store in freezer, under -20°C
form  Powder
pka 10.72±0.20(Predicted)
color  White to cream
Water Solubility  Very soluble in water.
Sensitive  Moisture Sensitive
BRN  878265
CAS DataBase Reference 4114-31-2(CAS DataBase Reference)
NIST Chemistry Reference Hydrazinecarboxylic acid, ethyl ester(4114-31-2)
EPA Substance Registry System Hydrazinecarboxylic acid, ethyl ester (4114-31-2)

Safety information for Ethyl carbazate

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes P261:Avoid breathing dust/fume/gas/mist/vapours/spray.
P264:Wash hands thoroughly after handling.
P264:Wash skin thouroughly after handling.
P271:Use only outdoors or in a well-ventilated area.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352:IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for Ethyl carbazate

InChIKey VYSYZMNJHYOXGN-UHFFFAOYSA-N

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