Potassium tetrachloroplatinate(II)
Synonym(s):Potassium platinum(II) chloride
- CAS NO.:10025-99-7
- Empirical Formula: Cl4KPt-
- Molecular Weight: 375.98
- MDL number: MFCD00011378
- EINECS: 233-050-9
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-11-06 18:33:45
What is Potassium tetrachloroplatinate(II)?
Chemical properties
Red/Brown, Tetragonal Crystals
The Uses of Potassium tetrachloroplatinate(II)
In photography, in acid toning baths.
The Uses of Potassium tetrachloroplatinate(II)
Potassium tetrachloroplatinate solution is used in the preparation of platinum (Pt) nanoparticles. Ligands like ammonia or triphenyl phosphine can able to replace the chloride ligands to afford various derivatives. The replacement by ammonia results in the preparation of cisplatin, which is used in the cancer treatment. Further, it is used as catalyst in the hydroarylation reaction.
What are the applications of Application
Potassium tetrachloroplatinate (II) is an useful reagent in the preparation of other platinum coordination complexes
General Description
Potassium tetrachloroplatinate(II) is a ruby red crystalline solid and can be prepared by reacting potassium hexachloroplatinate (IV) with cuprous chloride.
Flammability and Explosibility
Non flammable
Safety Profile
Human poison by ingestion. Poison experimentally by intraperitoneal route. Corrosive to human skin by intradermal route. Mutation data reported. Human systemic effects: eosinophha, gastritis, renal function tests depressed. When heated to decomposition it emits toxic fumes of Cland K2O. Used as a catalyst for hydroformulations, photocatalysts, and dissociation of water. See also PLATINUM COMPOUNDS.
Purification Methods
It forms crystals from aqueous 0.75M HCl (20mL/g) between 100o and 0o. Wash them with ice-cold water and dry.
Properties of Potassium tetrachloroplatinate(II)
Melting point: | 250°C |
Density | 3.38 g/mL at 25 °C(lit.) |
storage temp. | Inert atmosphere,Room Temperature |
solubility | soluble in Water |
form | Crystals or Crystalline Powder |
color | Red-brown |
Specific Gravity | 3.38 |
Water Solubility | 10 g/L (20 ºC) |
Sensitive | Hygroscopic |
Merck | 14,7682 |
Exposure limits | ACGIH: TWA 0.002 mg/m3 NIOSH: IDLH 4 mg/m3; TWA 0.002 mg/m3 |
Stability: | Stable. Incompatible with acids, strong oxidizing agents. |
CAS DataBase Reference | 10025-99-7(CAS DataBase Reference) |
EPA Substance Registry System | Platinate(2-), tetrachloro-, dipotassium, (SP-4-1)- (10025-99-7) |
Safety information for Potassium tetrachloroplatinate(II)
Signal word | Danger |
Pictogram(s) |
Corrosion Corrosives GHS05 Skull and Crossbones Acute Toxicity GHS06 Health Hazard GHS08 |
GHS Hazard Statements |
H301:Acute toxicity,oral H315:Skin corrosion/irritation H317:Sensitisation, Skin H318:Serious eye damage/eye irritation H334:Sensitisation, respiratory |
Precautionary Statement Codes |
P280:Wear protective gloves/protective clothing/eye protection/face protection. P302+P352:IF ON SKIN: wash with plenty of soap and water. |
Computed Descriptors for Potassium tetrachloroplatinate(II)
InChIKey | RVRDLMCWUILSAH-UHFFFAOYSA-J |
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