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HomeProduct name listPotassium tetrachloroplatinate(II)

Potassium tetrachloroplatinate(II)

Synonym(s):Potassium platinum(II) chloride

  • CAS NO.:10025-99-7
  • Empirical Formula: Cl4KPt-
  • Molecular Weight: 375.98
  • MDL number: MFCD00011378
  • EINECS: 233-050-9
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-11-06 18:33:45
Potassium tetrachloroplatinate(II) Structural

What is Potassium tetrachloroplatinate(II)?

Chemical properties

Red/Brown, Tetragonal Crystals

The Uses of Potassium tetrachloroplatinate(II)

In photography, in acid toning baths.

The Uses of Potassium tetrachloroplatinate(II)

Potassium tetrachloroplatinate solution is used in the preparation of platinum (Pt) nanoparticles. Ligands like ammonia or triphenyl phosphine can able to replace the chloride ligands to afford various derivatives. The replacement by ammonia results in the preparation of cisplatin, which is used in the cancer treatment. Further, it is used as catalyst in the hydroarylation reaction.

What are the applications of Application

Potassium tetrachloroplatinate (II) is an useful reagent in the preparation of other platinum coordination complexes

General Description

Potassium tetrachloroplatinate(II) is a ruby red crystalline solid and can be prepared by reacting potassium hexachloroplatinate (IV) with cuprous chloride.

Flammability and Explosibility

Non flammable

Safety Profile

Human poison by ingestion. Poison experimentally by intraperitoneal route. Corrosive to human skin by intradermal route. Mutation data reported. Human systemic effects: eosinophha, gastritis, renal function tests depressed. When heated to decomposition it emits toxic fumes of Cland K2O. Used as a catalyst for hydroformulations, photocatalysts, and dissociation of water. See also PLATINUM COMPOUNDS.

Purification Methods

It forms crystals from aqueous 0.75M HCl (20mL/g) between 100o and 0o. Wash them with ice-cold water and dry.

Properties of Potassium tetrachloroplatinate(II)

Melting point: 250°C
Density  3.38 g/mL at 25 °C(lit.)
storage temp.  Inert atmosphere,Room Temperature
solubility  soluble in Water
form  Crystals or Crystalline Powder
color  Red-brown
Specific Gravity 3.38
Water Solubility  10 g/L (20 ºC)
Sensitive  Hygroscopic
Merck  14,7682
Exposure limits ACGIH: TWA 0.002 mg/m3
NIOSH: IDLH 4 mg/m3; TWA 0.002 mg/m3
Stability: Stable. Incompatible with acids, strong oxidizing agents.
CAS DataBase Reference 10025-99-7(CAS DataBase Reference)
EPA Substance Registry System Platinate(2-), tetrachloro-, dipotassium, (SP-4-1)- (10025-99-7)

Safety information for Potassium tetrachloroplatinate(II)

Signal word Danger
Pictogram(s)
ghs
Corrosion
Corrosives
GHS05
ghs
Skull and Crossbones
Acute Toxicity
GHS06
ghs
Health Hazard
GHS08
GHS Hazard Statements H301:Acute toxicity,oral
H315:Skin corrosion/irritation
H317:Sensitisation, Skin
H318:Serious eye damage/eye irritation
H334:Sensitisation, respiratory
Precautionary Statement Codes P280:Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352:IF ON SKIN: wash with plenty of soap and water.

Computed Descriptors for Potassium tetrachloroplatinate(II)

InChIKey RVRDLMCWUILSAH-UHFFFAOYSA-J

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