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HomeProduct name listDiphenic anhydride

Diphenic anhydride

Synonym(s):2,2′-Biphenyldicarboxylic acid anhydride;Diphenic acid anhydride

  • CAS NO.:6050-13-1
  • Empirical Formula: C14H8O3
  • Molecular Weight: 224.21
  • MDL number: MFCD00004993
  • EINECS: 227-950-0
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2023-04-23 13:52:06
Diphenic anhydride Structural

What is Diphenic anhydride?

Chemical properties

Powder

Purification Methods

After removing free acid by extraction with cold aqueous Na2CO3, the residue is crystallised from acetic anhydride and dried at 100o. Acetic anhydride converts the acid to the anhydride. It also crystallises from *C6H6 (m 219o) or chlorobenzene (m 224.5-225.5o). [Beilstein 17 H 526, 17 II 495, 17 III/IV 6425.]

Properties of Diphenic anhydride

Melting point: 225-227 °C (lit.)
Boiling point: 325.61°C (rough estimate)
Density  1.2337 (rough estimate)
refractive index  1.5400 (estimate)
storage temp.  Inert atmosphere,Room Temperature
form  Crystalline Powder or Flakes
color  White to beige or grayish-brown
Water Solubility  decomposes
Sensitive  Moisture Sensitive
BRN  171255
CAS DataBase Reference 6050-13-1(CAS DataBase Reference)
NIST Chemistry Reference 2,2'-Biphenyldicarboxylic anhydride(6050-13-1)
EPA Substance Registry System Dibenz[c,e]oxepin-5,7-dione (6050-13-1)

Safety information for Diphenic anhydride

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes P261:Avoid breathing dust/fume/gas/mist/vapours/spray.
P264:Wash hands thoroughly after handling.
P264:Wash skin thouroughly after handling.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P304+P340:IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405:Store locked up.

Computed Descriptors for Diphenic anhydride

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