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HomeProduct name listDiethyl 2-bromo-2-methylmalonate

Diethyl 2-bromo-2-methylmalonate

  • CAS NO.:29263-94-3
  • Empirical Formula: C8H13BrO4
  • Molecular Weight: 253.09
  • MDL number: MFCD00009125
  • EINECS: 249-541-6
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-08-08 18:06:34
Diethyl 2-bromo-2-methylmalonate Structural

What is Diethyl 2-bromo-2-methylmalonate?

Chemical properties

CLEAR COLOURLESS LIQUID

The Uses of Diethyl 2-bromo-2-methylmalonate

Diethyl 2-bromo-2-methylmalonate was used to investigate the 1,2,2,6,6-pentamethylpiperidine as an effective reducing agent for the radical chain conversion of primary bromoesters to the corresponding esters. It was used in the synthesis of polystyrene macroinitiator via atom transfer radical polymerization.

General Description

Diethyl 2-bromo-2-methylmalonate acts as initiator during the atom transfer radical polymerization of methyl methacrylate.

Properties of Diethyl 2-bromo-2-methylmalonate

Boiling point: 105-106 °C (5 mmHg)
Density  1.325 g/mL at 25 °C (lit.)
refractive index  n20/D 1.449(lit.)
Flash point: >230 °F
storage temp.  Inert atmosphere,Room Temperature
form  clear liquid
color  Colorless to Almost colorless
BRN  1779673
CAS DataBase Reference 29263-94-3(CAS DataBase Reference)

Safety information for Diethyl 2-bromo-2-methylmalonate

Signal word Danger
Pictogram(s)
ghs
Corrosion
Corrosives
GHS05
GHS Hazard Statements H314:Skin corrosion/irritation
Precautionary Statement Codes P280:Wear protective gloves/protective clothing/eye protection/face protection.
P363:Wash contaminated clothing before reuse.
P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405:Store locked up.

Computed Descriptors for Diethyl 2-bromo-2-methylmalonate

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