DIETHYL DIETHYLMALONATE
Synonym(s):Diethyl 3,3-pentanedicarboxylate
- CAS NO.：77-25-8
- Empirical Formula: C11H20O4
- Molecular Weight: 216.27
- MDL number: MFCD00009132
- EINECS: 201-016-2
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-06-17 17:12:53
What is DIETHYL DIETHYLMALONATE?
Chemical properties
clear colorless liquid. Quite powerful, fruity, Pear-like odor.
The Uses of DIETHYL DIETHYLMALONATE
Diethyl Diethylmalonate is an intermediate in the synthesis of Barbital (B118500), a prototype of the barbiturate hypnotics.
The Uses of DIETHYL DIETHYLMALONATE
manufacture of barbiturates.
Production Methods
This ester has been suggested for use in flavor compositions, but it is not sufficiently stable enough to become very popular. The ester has occasionally found use in perfume compositions, mainly as a modifier in fruity notes, winey top note bases, etc. Diethyl diethylmalonate is produced (several methods) e. g. by condensing Ethyl acetate with Ethyl oxalate, heat the resultant Oxaloacetic ester, and esterify the formed Diethyl malonic acid.
Synthesis Reference(s)
Journal of the American Chemical Society, 64, p. 578, 1942 DOI: 10.1021/ja01255a034
Properties of DIETHYL DIETHYLMALONATE
| Boiling point: | 228-230 °C (lit.) |
| Density | 0.99 g/mL at 25 °C (lit.) |
| refractive index | n |
| Flash point: | 202 °F |
| storage temp. | Sealed in dry,Room Temperature |
| solubility | Chloroform, Methanol (Sparingly) |
| form | Oil |
| color | Clear Colourless |
| Specific Gravity | 0.988 (20/4℃) |
| Merck | 14,3823 |
| CAS DataBase Reference | 77-25-8(CAS DataBase Reference) |
| EPA Substance Registry System | Propanedioic acid, diethyl-, diethyl ester (77-25-8) |
Safety information for DIETHYL DIETHYLMALONATE
| Signal word | Warning |
| Pictogram(s) |
 Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation |
| Precautionary Statement Codes |
P280:Wear protective gloves/protective clothing/eye protection/face protection. P302+P352:IF ON SKIN: wash with plenty of soap and water. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. P332+P313:IF SKIN irritation occurs: Get medical advice/attention. P337+P313:IF eye irritation persists: Get medical advice/attention. |
Computed Descriptors for DIETHYL DIETHYLMALONATE
Abamectin manufacturer
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product: Diethylmalonic acid diethyl ester 98%
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