Dibenzyl azodicarboxylate
- CAS NO.：2449-05-0
- Empirical Formula: C16H14N2O4
- Molecular Weight: 298.29
- MDL number: MFCD00016737
- EINECS: 219-508-0
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-06-05 17:10:12
What is Dibenzyl azodicarboxylate?
Chemical properties
yellow to orange crystalline powder
The Uses of Dibenzyl azodicarboxylate
Dibenzyl azodicarboxylate is a reagent used in the synthesis of Minocycline-d6 (M344797). Minocycline-d6 is a labeled second generation tetracycline antibiotic. Antibacterial.
The Uses of Dibenzyl azodicarboxylate
Dibenzyl azodicarboxylate was used as electrophilic reagent in the synthesis of C-glycosyl α-amino acids via proline-catalyzed α-amination of C-glycosylalkyl aldehydes. It was used in enantioselective synthesis of optically active pyrazolidine derivatives.
General Description
Dibenzyl azodicarboxylate undergoes[4+2] cycloaddition reaction with glycal to yield 2-aminoglycosides.
Synthesis
PIDA (phenyliodine diacetate) and DCM (dichloromethane) were added to compound dibenzyl hydrazine-1,2-dicarboxylate, and the mixture was reacted with stirring at room temperature for 30 minutes to obtain DBAD (dibenzyl azodicarboxylate) in a yield of 97%.
Properties of Dibenzyl azodicarboxylate
| Melting point: | 43-47 °C (lit.) |
| Boiling point: | 439.72°C (rough estimate) |
| Density | 1.2028 (rough estimate) |
| refractive index | 1.6240 (estimate) |
| Flash point: | >230 °F |
| storage temp. | 2-8°C |
| form | Crystalline Powder |
| color | Yellow to orange |
| Sensitive | Light Sensitive |
| BRN | 2298734 |
| InChI | InChI=1S/C16H14N2O4/c19-15(21-11-13-7-3-1-4-8-13)17-18-16(20)22-12-14-9-5-2-6-10-14/h1-10H,11-12H2 |
| CAS DataBase Reference | 2449-05-0(CAS DataBase Reference) |
| EPA Substance Registry System | Diazenedicarboxylic acid, bis(phenylmethyl) ester (2449-05-0) |
Safety information for Dibenzyl azodicarboxylate
| Signal word | Warning |
| Pictogram(s) |
 Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
| Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P271:Use only outdoors or in a well-ventilated area. P280:Wear protective gloves/protective clothing/eye protection/face protection. P302+P352:IF ON SKIN: wash with plenty of soap and water. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for Dibenzyl azodicarboxylate
| InChIKey | IRJKSAIGIYODAN-ISLYRVAYSA-N |
| SMILES | N(C(OCC1=CC=CC=C1)=O)=NC(OCC1=CC=CC=C1)=O |
Abamectin manufacturer
AMINO ORGANICS
1Y
Phone:+919866989891
Whatsapp: +91 9866989891
product: DibenzylAzodicarboxylate 99%
Paushak Limited
1Y
Phone:+91-9727736899
Whatsapp: +91 9727736899
product: Azodicarboxylic acid dibenzyl ester 2449-05-0 98%
Tosco Pharmachem Pvt Ltd
1Y
Phone:+91-9573336677
Whatsapp: +91 9573336677
product: 2449-05-0 Azodicarboxylic acid dibenzyl ester 99%
New Products
6-Bromo 2-Iodo Indole Pyridine 2,4,6-Tricarboxaldehyde Fosfomycin EP impurity D Rimegepant Impurity 3 Ivermectin EP Impurity B Tubulysin H Tubulysin F Tubulysin G Tubulysin I Imeglimin Hydrochloride IH (1R,2S)-2-(3,4-Difluorophenyl)cyclopropanamine 2-[2-[3(S)-3[2-(7-chloro-2-quinolinyl) ethenyl] phenyl-3- hydroxyl propyl] phenyl]-2-propanol 2-(1-(Mercaptomethyl) cyclopropyl) acetonitrile Fuel shell Calcium Sodium Phosphosilicate IH Methyl 4-amino-3-(dihexylamino)benzoate (S)-Methyl 2-((tert-butoxycarbonyl)amino)-3-((S)-2-oxopyrrolidin-3-yl)propanoate 3-Morpholino-5,6-dihydropyridin-2(1H)-one 2-Ethoxy-4-nitrobenzoic acid 4-(Azidomethyl)-3-chloropyridine 3,6-Bis(4-iodophenyl)-2,5-dihydropyrrolo[3,4-c]pyrrole-1,4-dione 6-Bromo-2-methoxy-3-(4-methyl-1H-imidazol-1-yl)pyridine Ethyl (2Z)-chloro((4-methoxyphenyl)hydrazono)acetate tert-butyl2-amino-4H,5H,6H-cyclopenta[b]thiophene-3-carboxylateRelated products of tetrahydrofuran
You may like
-
2449-05-0 Dibenzyl Azodicarboxylate 99%View Details
2449-05-0 -
2449-05-0 98%View Details
2449-05-0 -
DibenzylAzodicarboxylate 99%View Details
2449-05-0 -
Azodicarboxylic acid dibenzyl ester 2449-05-0 98%View Details
2449-05-0 -
Dibenzyl azodicarboxylate CAS 2449-05-0View Details
2449-05-0 -
Dibenzyl azodicarboxylate 96% CAS 2449-05-0View Details
2449-05-0 -
Dibenzyl azodicarboxylate 95.00% CAS 2449-05-0View Details
2449-05-0 -
Dibenzyl azodicarboxylate CAS 2449-05-0View Details
2449-05-0
Statement: All products displayed on this website are only used for non medical purposes such as industrial applications or scientific research, and cannot be used for clinical diagnosis or treatment of humans or animals. They are not medicinal or edible.