COPPER(I) TRIFLUOROMETHANESULFONATE BENZENE COMPLEX
Synonym(s):Copper(I) triflate benzene complex;Cuprous trifluoromethanesulfonate benzene complex;Trifluoromethanesulfonic acid copper(I) salt benzene complex
- CAS NO.：42152-46-5
- Empirical Formula: C8H6Cu2F6O6S2
- Molecular Weight: 503.34
- MDL number: MFCD00043300
- EINECS: 255-686-6
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-06-08 17:06:36
What is COPPER(I) TRIFLUOROMETHANESULFONATE BENZENE COMPLEX?
Chemical properties
Grey-greenish powder
The Uses of COPPER(I) TRIFLUOROMETHANESULFONATE BENZENE COMPLEX
Copper(I) trifluoromethanesulfonate benzene complex can be used as a catalyst:
- To synthesize enol-esters via copper(I) carboxylate intermediate formation.
- In the enantioselective allylic oxidation of cyclic alkenes.
- To prepare 2,5-disubstituted pyrrolidine derivatives from N-alkenyl, alkynyl and alkyl N-benzoyloxysulfonamides via the sulfonamidyl radical formation.
It can also be used in combination with amino acid-based chiral phosphine ligands to catalyze asymmetric conjugate additions of alkylzincs to acyclic α,β-unsaturated ketones, affording β-alkylcarbonyls in high yield and with excellent enantioselectivity.
What are the applications of Application
Copper(I) trifluoromethanesulfonate benzene complex is catalyzes asymmetric conjugate additions
Properties of COPPER(I) TRIFLUOROMETHANESULFONATE BENZENE COMPLEX
| Melting point: | 160 °C (dec.) (lit.) |
| Flash point: | 45 °F |
| storage temp. | Inert atmosphere,2-8°C |
| form | Powder |
| color | Gray-greenish |
| CAS DataBase Reference | 42152-46-5 |
Safety information for COPPER(I) TRIFLUOROMETHANESULFONATE BENZENE COMPLEX
| Signal word | Warning |
| Pictogram(s) |
 Flame Flammables GHS02 |
| GHS Hazard Statements |
H228:Flammable solids |
| Precautionary Statement Codes |
P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking. P240:Ground/bond container and receiving equipment. P241:Use explosion-proof electrical/ventilating/lighting/…/equipment. P280:Wear protective gloves/protective clothing/eye protection/face protection. P370+P378:In case of fire: Use … for extinction. |
Computed Descriptors for COPPER(I) TRIFLUOROMETHANESULFONATE BENZENE COMPLEX
| InChIKey | OGHGYDFTMBZZJU-UHFFFAOYSA-M |
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