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HomeProduct name listClethodim

Clethodim

Synonym(s):2-{(E)-1-[(E)-3-Chloroallyloxyimino]propyl}-5-[2-(ethylthio)propyl]-3-hydroxy-2-cyclohexen-1-one

  • CAS NO.:99129-21-2
  • Empirical Formula: C17H26ClNO3S
  • Molecular Weight: 359.91
  • MDL number: MFCD01632327
  • EINECS: 000-000-0
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-07-24 17:31:20
Clethodim Structural

What is Clethodim?

Chemical properties

Clear Yellow Oil

The Uses of Clethodim

Systemic graminicide. Post-emergent herbicide.

Definition

ChEBI: Clethodim is an oxime O-ether resulting from the formal conversion ot the acyclic keto group of 5-[2-(ethylsulfanyl)propyl]-3-hydroxy-2-propionylcyclohex-2-en-1-one to the corresponding oxime with subsequent O-alkylation of the oxime by an (E)-3-chloroallyl group. It is used as a selective postemergence herbicide for the control of annual and perennial grasses in numerous crops, including alfalfa, celery, clover, conifers, cotton, cranberries, garlic, onions, ornamentals, peanuts, soybeans, strawberries, sugarbeet, sunflowers, and vegetables; the (-)-enantiomer has been reported to be more active than the (+)-enantiomer. It has a role as a herbicide and an EC 6.4.1.2 (acetyl-CoA carboxylase) inhibitor. It is an organic sulfide, a cyclic ketone, an organochlorine compound, an oxime O-ether, a beta-diketone and an enol.

Agricultural Uses

Herbicide: Not approved for use in EU countries. A selective post-emergence herbicide used to control annual and perennial grasses to a range of crops including cotton, flax, peanuts, soybeans, sugarbeets, potatoes, alfalfa, sunflowers and most vegetables.

Trade name

CLETODIME®; PRISM®; RE 45601; SELECT®

Properties of Clethodim

Melting point: <25 °C
Boiling point: 472.6±55.0 °C(Predicted)
Density  1.18±0.1 g/cm3(Predicted)
storage temp.  0-6°C
solubility  Chloroform (Sparingly, Sonicated), Ethyl Acetate (Slightly), Methanol (Sparingly
form  neat
pka 4.28±0.25(Predicted)
form  Liquid
color  Light Yellow to Dark Yellow
Stability: Hygroscopic
CAS DataBase Reference 99129-21-2(CAS DataBase Reference)
EPA Substance Registry System Clethodim (99129-21-2)

Safety information for Clethodim

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H302:Acute toxicity,oral
H317:Sensitisation, Skin
Precautionary Statement Codes P261:Avoid breathing dust/fume/gas/mist/vapours/spray.
P264:Wash hands thoroughly after handling.
P264:Wash skin thouroughly after handling.
P270:Do not eat, drink or smoke when using this product.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312:IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P302+P352:IF ON SKIN: wash with plenty of soap and water.

Computed Descriptors for Clethodim

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