Clethodim
Synonym(s):2-{(E)-1-[(E)-3-Chloroallyloxyimino]propyl}-5-[2-(ethylthio)propyl]-3-hydroxy-2-cyclohexen-1-one
- CAS NO.:99129-21-2
- Empirical Formula: C17H26ClNO3S
- Molecular Weight: 359.91
- MDL number: MFCD01632327
- EINECS: 000-000-0
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-07-24 17:31:20
What is Clethodim?
Chemical properties
Clear Yellow Oil
The Uses of Clethodim
Systemic graminicide. Post-emergent herbicide.
Definition
ChEBI: Clethodim is an oxime O-ether resulting from the formal conversion ot the acyclic keto group of 5-[2-(ethylsulfanyl)propyl]-3-hydroxy-2-propionylcyclohex-2-en-1-one to the corresponding oxime with subsequent O-alkylation of the oxime by an (E)-3-chloroallyl group. It is used as a selective postemergence herbicide for the control of annual and perennial grasses in numerous crops, including alfalfa, celery, clover, conifers, cotton, cranberries, garlic, onions, ornamentals, peanuts, soybeans, strawberries, sugarbeet, sunflowers, and vegetables; the (-)-enantiomer has been reported to be more active than the (+)-enantiomer. It has a role as a herbicide and an EC 6.4.1.2 (acetyl-CoA carboxylase) inhibitor. It is an organic sulfide, a cyclic ketone, an organochlorine compound, an oxime O-ether, a beta-diketone and an enol.
Agricultural Uses
Herbicide: Not approved for use in EU countries. A selective post-emergence herbicide used to control annual and perennial grasses to a range of crops including cotton, flax, peanuts, soybeans, sugarbeets, potatoes, alfalfa, sunflowers and most vegetables.
Trade name
CLETODIME®; PRISM®; RE 45601; SELECT®
Properties of Clethodim
Melting point: | <25 °C |
Boiling point: | 472.6±55.0 °C(Predicted) |
Density | 1.18±0.1 g/cm3(Predicted) |
storage temp. | 0-6°C |
solubility | Chloroform (Sparingly, Sonicated), Ethyl Acetate (Slightly), Methanol (Sparingly |
form | neat |
pka | 4.28±0.25(Predicted) |
form | Liquid |
color | Light Yellow to Dark Yellow |
Stability: | Hygroscopic |
CAS DataBase Reference | 99129-21-2(CAS DataBase Reference) |
EPA Substance Registry System | Clethodim (99129-21-2) |
Safety information for Clethodim
Signal word | Warning |
Pictogram(s) |
Exclamation Mark Irritant GHS07 |
GHS Hazard Statements |
H302:Acute toxicity,oral H317:Sensitisation, Skin |
Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P270:Do not eat, drink or smoke when using this product. P280:Wear protective gloves/protective clothing/eye protection/face protection. P301+P312:IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell. P302+P352:IF ON SKIN: wash with plenty of soap and water. |
Computed Descriptors for Clethodim
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