Propyl butyrate
Synonym(s):n-Propyl-n-butanoate
- CAS NO.:105-66-8
- Empirical Formula: C7H14O2
- Molecular Weight: 130.18
- MDL number: MFCD00009396
- EINECS: 203-320-0
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-11-28 16:31:44
What is Propyl butyrate?
Chemical properties
Clear colorless liquid
Chemical properties
Propyl butyrate has a pineapple and apricot-like odor with a sweet, fruity flavor of banana and pineapple. The odor is also described as sharp, pungent, rancid, sweaty and sickening.
Occurrence
Reported found in fresh apple, cooked apple, apricot, banana, lemon papaya, Camembert cheese, Gruyere de Comte cheese, provolone cheese, purple passion fruit juice, apple juice, rum, fresh plums, jack fruit, ceriman or pinanona (Monstera deliciosa Liebm.), papaya, spineless monkey orange, starfruit, kiwifruit, wood apple and cherimoya.
The Uses of Propyl butyrate
Solvent mixture for cellulose ethers.
Preparation
From propyl alcohol and butyric acid in the presence of p-toluenesulfonic acid in benzene solution at the boil.
Definition
ChEBI: Propyl butyrate is a butyrate ester resulting from the formal condensation of the hydroxy group of propanol with the carboxy group of butyric acid. It has a role as a human metabolite, a plant metabolite and an insect attractant. It is functionally related to a propan-1-ol.
Aroma threshold values
Detection: 0.8 to 124 ppb
Taste threshold values
Taste characteristics at 20 ppm: sweet, fruity, tutti-frutti, bubble gum and pineapple-like, with a slight green nuance.
Synthesis Reference(s)
The Journal of Organic Chemistry, 58, p. 6421, 1993 DOI: 10.1021/jo00075a043
General Description
Natural Occurrence: Apple, banana, kiwi, melon, papaya, passion fruit, rum and strawberry.
Hazard
Irritant to mucous membranes, narcotic in high concentration.
Biochem/physiol Actions
Taste at 20 ppm
Properties of Propyl butyrate
Melting point: | 95°C |
Boiling point: | 142-143 °C (lit.) |
Density | 0.873 g/mL at 25 °C (lit.) |
refractive index | n |
FEMA | 2934 | PROPYL BUTYRATE |
Flash point: | 102 °F |
storage temp. | Flammables area |
form | clear liquid |
color | Colorless to Almost colorless |
Odor | at 100.00 %. fruity sweet apricot pineapple rancid sweaty |
Odor Threshold | 0.011ppm |
Water Solubility | 1.614g/L(17 ºC) |
JECFA Number | 150 |
Merck | 14,7846 |
BRN | 1745552 |
Dielectric constant | 4.3(20℃) |
CAS DataBase Reference | 105-66-8(CAS DataBase Reference) |
NIST Chemistry Reference | Butanoic acid, propyl ester(105-66-8) |
EPA Substance Registry System | Butanoic acid, propyl ester (105-66-8) |
Safety information for Propyl butyrate
Signal word | Warning |
Pictogram(s) |
Flame Flammables GHS02 Exclamation Mark Irritant GHS07 |
GHS Hazard Statements |
H226:Flammable liquids H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
Precautionary Statement Codes |
P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking. P302+P352:IF ON SKIN: wash with plenty of soap and water. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for Propyl butyrate
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