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HomeProduct name listcis-3-Hexenyl 2-methylbutanoate

cis-3-Hexenyl 2-methylbutanoate

  • CAS NO.:53398-85-9
  • Empirical Formula: C11H20O2
  • Molecular Weight: 184.28
  • MDL number: MFCD00036530
  • EINECS: 258-517-4
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-07-19 18:29:52
cis-3-Hexenyl 2-methylbutanoate Structural

What is cis-3-Hexenyl 2-methylbutanoate?

Chemical properties

cis-3-Hexenyl-2-methylbutyrate has a strong, warm, fruity odor like unripe apple and pineapple. It has a sweet, applelike taste

Occurrence

Reported found in apricot, scotch, spearmint, menthe oils, fresh plum and black tea

Definition

ChEBI: Cis-3-Hexenyl 2-methylbutanoate is a fatty acid ester.

What are the applications of Application

In spite of the “unripe” odour in high concentration, Cis-3-Hexenyl 2-methylbutanoate produces very “ripe” fruity notes in dilutions and combinations with suitable blenders. It has good tenacity. It is found in perfume compositions and artificial essential oils as a “naturalized” freshener-modifier for the greener notes of lower esters of Hexcnol. It blends particularly well with Lavender, Lavandin, Clary Sage and Geranium. In flavours, it offers good opportunities for variation of the Apple and Pine-apple themes with conventional materials; in Plum, Peach and Apricot, where overly sweet fruity notes may be prevalent, it will supply sufficient freshness to compensate for those heavy Aromas of other chemicals. Esters of alpha- Mcthylbutyric acid have become quite popular since more and more such esters have been identified in natural products. Approved for use in food flavours by the American F. R. 1965.

What are the applications of Application

Cis-3-Hexenyl 2-methyl butanoate is produced from cis-3-Hcxenol by esterification with alpha-Methylbutync acid under azeotropic conditions.

Taste threshold values

Taste characteristics at 10 ppm: green, fruity, sweet, juicy and pear-like with vegetative nuances

Properties of cis-3-Hexenyl 2-methylbutanoate

Melting point: -58.7°C (estimate)
Boiling point: 228.24°C (estimate)
Density  0.878 g/mL at 25 °C(lit.)
refractive index  n20/D 1.432(lit.)
FEMA  3497 | 3-HEXENYL 2-METHYLBUTANOATE
Flash point: 182 °F
storage temp.  Sealed in dry,2-8°C
solubility  Insoluble in water, soluble in alcohol and oils.
form  clear liquid
color  Colorless to Almost colorless
Odor at 10.00 % in propylene glycol. fresh green apple sweet fruity pear
CAS DataBase Reference 53398-85-9(CAS DataBase Reference)
EPA Substance Registry System (Z)-3-Hexenyl 2-methylbutyrate (53398-85-9)

Safety information for cis-3-Hexenyl 2-methylbutanoate

Signal word Warning
Pictogram(s)
ghs
Environment
GHS09
GHS Hazard Statements H411:Hazardous to the aquatic environment, long-term hazard
Precautionary Statement Codes P273:Avoid release to the environment.

Computed Descriptors for cis-3-Hexenyl 2-methylbutanoate

InChIKey JKKGTSUICJWEKB-SREVYHEPSA-N

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