Chlorobis(ethylene)rhodium (I) dimer
Synonym(s):[Rh(C2H4)2Cl]2;Bis[chlorobis(ethylene)rhodium];Bis[chlorodiethylenerhodium];Chlorobis(ethylene)rhodium dimer;Dichlorotetra(ethene)dirhodium
- CAS NO.：12081-16-2
- Empirical Formula: C8H16Cl2Rh2
- Molecular Weight: 388.93
- MDL number: MFCD00013206
- EINECS: 235-145-0
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-04-23 13:52:06
What is Chlorobis(ethylene)rhodium (I) dimer?
Chemical properties
red-brown powder
The Uses of Chlorobis(ethylene)rhodium (I) dimer
Chlorobis(ethylene)rhodium(I) dimer is used as a precursor to rhodium(I) norbornadiene catalyst, which is used in an asymmetric 1,4-addition of arylboronic acids to cyclic enones. Further, it serves as an important organic intermediate. It catalyzes the dimerization of ethylene to 1-butene. It is also used in the preparation of homogeneous catalysts.
The Uses of Chlorobis(ethylene)rhodium (I) dimer
Precursor to Rh(I) norbornadiene catalyst used in an asymmetric 1,4-addition of arylboronic acids to cyclic enones.
Properties of Chlorobis(ethylene)rhodium (I) dimer
| storage temp. | -20°C |
| solubility | Chloroform (Slightly, Heated, Sonicated), DMSO (Slightly, Heated, Sonicated), Me |
| form | Crystalline Powder or Chunks |
| color | Rust |
| Water Solubility | Sparingly soluble in ethanol, acetone, dioxane, chloroform and dichloromethane. Insoluble in water. |
| Sensitive | Air Sensitive |
| Exposure limits | ACGIH: TWA 0.01 mg/m3; TWA 1 mg/m3 NIOSH: IDLH 2 mg/m3; IDLH 100 mg/m3; TWA 0.001 mg/m3; TWA 0.1 mg/m3 |
| Stability: | Air Sensitive |
Safety information for Chlorobis(ethylene)rhodium (I) dimer
| Signal word | Warning |
| Pictogram(s) |
 Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H319:Serious eye damage/eye irritation |
| Precautionary Statement Codes |
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for Chlorobis(ethylene)rhodium (I) dimer
| InChIKey | OOQJCPOXJFCGCR-UHFFFAOYSA-L |
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