BIS(NORBORNADIENE)RHODIUM (I) TETRAFLUOROBORATE
Synonym(s):Bis(bicyclo[2.2.1]hepta-2,5-diene)rhodium tetrafluoroborate;Bis(norbornadiene)(tetrafluoroborato)rhodium;Bis(norbornadiene)rhodium(I) tetrafluoroborate;Rh(nbd)2BF4;Rh(nbd)2BF4
- CAS NO.：36620-11-8
- Empirical Formula: C14H8BF4Rh
- Molecular Weight: 365.93
- MDL number: MFCD00671775
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-04-23 13:52:06
What is BIS(NORBORNADIENE)RHODIUM (I) TETRAFLUOROBORATE?
Chemical properties
dark red
The Uses of BIS(NORBORNADIENE)RHODIUM (I) TETRAFLUOROBORATE
Bis{P,P'-1,5-diphenyl-3,7-bis[(4-hydrogenphosphonate)phenyl]-1,5,3,7-diazadiphosphocine} nickel(II) bromide (hydrogen bromide adduct) can be used as Synthetic nickel catalyst used for photocatalytic reduction of aqueous protons to hydrogen and catalyst containing phosphonate anchor groups for immobilation on metal oxide semiconductor surfaces, enabling light-driven hydrogen evolution.
The Uses of BIS(NORBORNADIENE)RHODIUM (I) TETRAFLUOROBORATE
Bis(norbornadiene)rhodium(I) tetrafluoroborate is used in hydrogenation, Isomerization reactions.
Reactions
Precursor for asymmetric hydrogenation reactions.
Properties of BIS(NORBORNADIENE)RHODIUM (I) TETRAFLUOROBORATE
| Melting point: | 209-211 °C |
| storage temp. | Inert atmosphere,Store in freezer, under -20°C |
| form | Powder |
| color | Red |
| Water Solubility | Fairly soluble in dichloromethane. Insoluble in water. |
| Sensitive | Air & Moisture Sensitive |
Safety information for BIS(NORBORNADIENE)RHODIUM (I) TETRAFLUOROBORATE
| Signal word | Danger |
| Pictogram(s) |
 Corrosion Corrosives GHS05 |
| GHS Hazard Statements |
H314:Skin corrosion/irritation |
| Precautionary Statement Codes |
P260:Do not breathe dust/fume/gas/mist/vapours/spray. P280:Wear protective gloves/protective clothing/eye protection/face protection. P363:Wash contaminated clothing before reuse. P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for BIS(NORBORNADIENE)RHODIUM (I) TETRAFLUOROBORATE
| InChIKey | NMZDXSXETNAOPO-UHFFFAOYSA-M |
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product: 36620-11-8 Bis(norbornadiene)rhodium(I) Tetrafluoroborate 98%
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