Chloro(1,5-cyclooctadiene)rhodium(I) dimer
Synonym(s):Chloro(1,5-cyclooctadiene)rhodium(I) dimer;Di-μ-chlorobis[(1,2,5,6-η)-1,5-cyclooctadiene]dirhodium;1,5-Cyclooctadienerhodium(I) chloride dimer;Bis(1,5-cyclooctadiene)dirhodium(I) dichloride;Di(μ-chloro)bis(1,5-cyclooctadiene)dirhodium(I)
- CAS NO.：12092-47-6
- Empirical Formula: C16H24Cl2Rh2
- Molecular Weight: 493.08
- MDL number: MFCD00012415
- EINECS: 235-157-6
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-12-18 14:15:30
What is Chloro(1,5-cyclooctadiene)rhodium(I) dimer?
Chemical properties
orange crystals
The Uses of Chloro(1,5-cyclooctadiene)rhodium(I) dimer
It is a widely used precursor to homogeneous catalysts. This is a chiral catalyst capable of asymmetrically hydrogenating certain prochiral alkenes. Chloro(1,5-cyclooctadiene)rhodium(I) dimer is also used in the synthesis of other metal ligands for use in catalysis.
The Uses of Chloro(1,5-cyclooctadiene)rhodium(I) dimer
Chloro(1,5-cyclooctadiene)rhodium(I) dimer ([Rh(COD)Cl]2) can be:
- Employed for the synthesis of rhodium complex of heterocyclic carbenes (NHCs).
- Modified and coated on the surface of ferrite magnetic nanoparticles for catalyzing hydroformylation reaction of olefins.
- Used for the synthesis of triple-layer structure to be used as a ring-opening polymerization catalyst.
- As an effective catalyst for dehydrogenation of amine-borane adducts (hydrogen storage materials) such as ammonia-borane.
What are the applications of Application
Chloro(1,5-cyclooctadiene)rhodium(I) dimer is a catalyst for coupling 1,3-dienes with activated hydrocarbons
General Description
This product has been enhanced for catalytic efficiency.
Flammability and Explosibility
Not classified
Properties of Chloro(1,5-cyclooctadiene)rhodium(I) dimer
| Melting point: | 243 °C (dec.) (lit.) |
| Density | 1.94[at 20℃] |
| vapor pressure | 0Pa at 25℃ |
| storage temp. | Inert atmosphere,Room Temperature |
| solubility | Soluble in chloroform, dichloromethane, and methanol. Sparingly soluble in most common solvents. |
| form | Crystals or Crystalline Powder |
| color | Orange to orange-brown |
| Water Solubility | 1.56g/L at 20℃ |
| Sensitive | Air Sensitive & Hygroscopic |
| Exposure limits | ACGIH: TWA 0.01 mg/m3; TWA 1 mg/m3 NIOSH: IDLH 2 mg/m3; IDLH 100 mg/m3; TWA 0.001 mg/m3; TWA 0.1 mg/m3 |
| Stability: | hygroscopic |
| NIST Chemistry Reference | Bis(1,5-cyclooctadienerhodium chloride)(12092-47-6) |
| EPA Substance Registry System | Rhodium, di-.mu.-chlorobis[(1,2,5,6-.eta.)-1,5-cyclooctadiene]di- (12092-47-6) |
Safety information for Chloro(1,5-cyclooctadiene)rhodium(I) dimer
| Signal word | Warning |
| Pictogram(s) |
 Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H319:Serious eye damage/eye irritation |
| Precautionary Statement Codes |
P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P280:Wear protective gloves/protective clothing/eye protection/face protection. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. P337+P313:IF eye irritation persists: Get medical advice/attention. |
Computed Descriptors for Chloro(1,5-cyclooctadiene)rhodium(I) dimer
Chloro(1,5-cyclooctadiene)rhodium(I) dimer manufacturer
Omkar Lab
1Y
Phone:91-9326135973
Whatsapp: +91-9326135973
product: Chloro-(1,5-cyclooctadiene)-rhodium dimer 98%
Johnson Matthey Chemicals India Pvt Ltd
1Y
Phone:+91-9711869003
Whatsapp: +91-9711869003
product: Chloro-(1,5-cyclooctadiene)-rhodium dimer 12092-47-6 98%
Omkar Lab
Maharashtra
Phone:91-9326135973
Whatsapp: 91-9326135973
product: Chloro-(1,5-cyclooctadiene)-rhodium dimer
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